109. Luo, M.; Hua, Y.; Zhuo, K.; Long, L.; Lin, X.; Deng, Z.; Lin, Z.; Zhang, H.; Chen, D.; Xia, H.* Carbolong Chemistry: Planar CCCCX-Type (X = N, O, S) Pentadentate Chelates by Formal [3+1] Cycloadditions of Metalla-Azirines with Terminal Alkynes. CCS Chemistry 2020, 2, 758-763.
108. Luo, M.; Sui, Y.; Lin, X.; Zhu, C.; Yan, Z.; Ruan, Y.; Zhang, H.;* Xia, H.* [3+2] Cycloaddition Reaction of Metallacyclopropene with Nitrosonium Ion: Isolation of Aromatic Metallaisoxazole. Chem. Commun. 2020, 56, 6806 - 6809.
107. Tang, C.; Zheng, J.; Ye, Y.; Liu, J.; Chen, L.; Yan, Z.; Chen, Z.; Chen, L.; Huang, X.; Bai, J.; Chen, Z.; Shi, J.; Xia, H.;* Hong, W.* Electric-Field-Induced Connectivity Switching in Single-Molecule Junctions. iScience 2020, 23, 100770.
106. Chen, Y.;† Yang, L.;† Zheng, W.; Ouyang, P.; Zhang, H.; Ruan, Y.; Weng, W.;* He, X.;* Xia, H.* Dynamic Polymer Network System Mediated by Radically Exchangeable Covalent Bond and Carbolong Complex. ACS Macro Lett. 2020, 9, 344-349.(Chen and Yang contributed equally to this work.)
105. Lu, Z.;† Zhu, Q.;† Cai, Y.; Chen, Z.; Zhuo, K.; Zhu, J.; Zhang, H.;* Xia, H.* Access to Tetracyclic Aromatics with Bridgehead Metals via Metalla-click Reactions. Sci. Adv. 2020, 6, eaay2535.(Lu and Zhu contributed equally to this work.)
104. Meng, S.; Zhang, M.; Yao, M.;* Qiu, Z.; Hong, Y.; Lan, W.; Xia, H.; Jin, X. Membrane Fouling and Performance of Flat Ceramic Membranes in the Application of Drinking Water Purification. Water 2019, 11, 2606.
103. Zhuo, Q.;† Zhang, H.;† Ding, L.; Lin, J.; Zhou, X.; Hua, Y.; Zhu, J.; Xia, H.* Rhodapentalenes: Pincer Complexes with Internal Aromaticity. iScience 2019, 19, 1214-1224.(Zhuo and Zhang contributed equally to this work.)
102. Luo, M.; Deng, Z.; Ruan, Y.; Cai, Y.; Zhuo, K.; Zhang, H.;* Xia, H. Reactions of Metallacyclopentadiene with Terminal Alkynes: Isolation and Characterization of Metallafulvenallene Complexes. Organometallics 2019, 38, 3053-3059.(ACS Editors’ Choice)
101. Huang, X.;† Tang, C.;† Li, J.;† Chen, L.-C.;† Zheng, J.; Zhang, P.; Le, J.; Li, R.; Li, X.; Liu, J.;* Yang, Y.; Shi, J.; Chen, Z.; Bai, M.; Zhang, H. L.; Xia, H.; Cheng, J.;* Tian, Z. Q.; Hong, W.* Electric Field-induced Selective Catalysis of Single-Molecule Reaction. Sci. Adv. 2019, 5, eaaw3072.(Huang, Tang, Li and Chen contributed equally to this work.)
100. Tang, C.; Chen, L.; Zhang, L.; Chen, Z.; Li, G.; Yan, Z.; Lin, L.; Liu, J.; Huang, L.; Ye, Y.; Hua, Y.; Shi, J.; Xia, H.;* Hong, W.* Multicenter-Bond-Based Quantum Interference in Charge Transport Through Single-Molecule Carborane Junctions. Angew. Chem., Int. Ed. 2019, 58, 10601-10605.
99. Chen, Z.;† Chen, L.;† Liu, J.; Li, R.; Tang, C.; Hua, Y.; Chen, L.; Shi, J.; Yang, Y.; Liu, J.; Zheng, J.; Chen, L.; Cao, J.; Chen, H.; Xia, H.;* Hong, W.* Modularized Tuning of Charge Transport through Highly Twisted and Localized Single-Molecule Junctions. J. Phys. Chem. Lett. 2019, 10, 3453-3458.(†Chen, Z.; and Chen, L. contributed equally to this work.)
98. Wu, F.; Huang, W.; Zhuo, K.; Hua, Y.; Lin, J.; He, G.;* Chen, J.; Nie, L.;* Xia, H.* Carbolong Complexes as Photothermal Materials. Chin. J. Org. Chem. 2019, 39, 1743-1752.
97. Deng, Z.; Zhu, C.; Hua, Y.; He, G.; Guo, Y.; Lu, R.; Cao, X.; Chen, J.;* Xia, H.* Synthesis and Characterization of Metallapentalenoxazetes from the [2+2] Cycloaddition of Metallapentalynes with Nitrosoarenes. Chem. Commun. 2019, 55, 6237-6240.
96. Lin, J.; Ding, L.; Zhuo, Q.; Zhang, H.;* Xia, H.* Formal [2+2+2] Cycloaddition Reaction of a Metal–Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex. Organometallics 2019, 25, 5077-5085.
95. Zhou, X.; Pang, X.; Nie, L.; Zhu, C.; Zhuo, K.; Zhuo, Q.; Chen, Z.; Liu, G.; Zhang, H.;* Lin, Z.; Xia, H. Successive Modification of Polydentate Complexes Gives Access to Planar Carbon- and Nitrogen-based Ligands. Nat. Commun. 2019, 10, 1488.
94. Li, J.; Lin, Y. M.;* Zhang, H.; Chen, Y.; Lin, Z.; Xia, H.* Access to Metal-Bridged Osmathiazine Derivatives by a Formal [4+2] Cyclization. Chem. - Eur. J. 2019, 25, 5077-5085.
93. Zhang, H.;† Zhao, H.;† Zhuo, K.; Hua, Y.; Chen, J.; He, X.;* Weng, W.;* Xia, H.* "Carbolong" Polymers with Near Infrared Triggered, Spatially Resolved and Rapid Self-Healing Properties. Polym. Chem. 2019, 10, 386-394.(†Zhang and Zhao contributed equally to this work.)
92. Li, J.; Kang, H.; Zhuo, K.; Zhuo, Q.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative. Chin. J. Chem. 2018, 36, 1156-1160.
91. Chen, Z.;† Wang, T.;† Sun, T.; Chen, Z.; Sheng, T.; Hong, Y.-H.; Nan, Z.-A.; Zhu, J.; Zhou, Z.-Y.;* Xia, H.;* Sun, S.-G. Nickel Complexes with Non-innocent Ligands as Highly Active Electrocatalysts for Hydrogen Evolution. Chin. J. Chem. 2018, 36, 1161-1164.(†Chen and Wang contributed equally to this work.)
90. Lu, Z.;† Lin, Q.;† Cai, Y.; Chen, S.; Chen, J.;* Wu, W.; He, X.;* Xia, H.* Cylindrical Nir-Responsive Metallopolymer Containing Möbius Metalla-Aromatics. ACS Macro Lett. 2018, 7, 1034-1038.(†Lu and Lin contributed equally to this work.)
89. Hua, Y.; Lan, Q.; Fei, J.; Tang, C.; Lin, J.; Zha, H.; Chen, S.; Lu, Y.; Chen, J.;* He, X.;* Xia, H. Metallapentalenofuran: Shifting Metallafuran Rings Promoted by Substituent Effects. Chem. - Eur. J. 2018, 24, 14531-14538.
88. Zhuo, Q.;† Zhang, H.;† Hua, Y.; Kang, H.; Zhou, X.; Lin, X.; Chen, Z.; Lin, J.; Zhuo, K.; Xia, H.* Constraint of a Ruthenium-Carbon Triple Bond to a Five-Membered Ring. Sci. Adv. 2018, 4 (6), eaat0336.(†Zhuo and Zhang contributed equally to this work.)
87. Zhu, C.; Xia, H.* Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metals. Acc. Chem. Res. 2018, 51, 1691-1700.
86. Zhou, X.; Li, Y.; Shao, Y.; Hua, Y.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes. Organometallics 2018, 37, 1788-1794.
85. Lin, Q.;† Li, S.;† Lin, J.;† Chen, M.; Lu, Z.; Tang, C.; Chen, Z.; He, X.; Chen, J.;* Xia, H.* Synthesis and Characterization of Photothermal Osmium Carbolong Complexes. Chem. - Eur. J. 2018, 24, 8375-8381.(†Lin, Q., Li, S. and Lin, J. contributed equally to this work.)
84. Zhou, X.; Huang, F.; Tang, C.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Xia, H. A Missing Member of Conjugated N-Heterocycles: Realizing Pyrido[1,2-Α]azepine by Reacting Ruthenium Alkenylcarbene Complex with Alkyne. Chem. Commun. 2018, 54, 4009-4012.
83. Wang, T.;† Chen, Z.-X.;† Chen, Y.-G.; Yang, L.-J.; Yang, X.-D.; Ye, J.-Y.; Xia, H.-P.; Zhou, Z.-Y.;* Sun, S.-G. Identifying the Active Site of N-Doped Graphene for Oxygen Reduction by Selective Chemical Modification. ACS Energy Lett. 2018, 3, 986-991.(†Wang and Chen contributed equally to this work.)
82. Wang, T.;† Chen, Z.-X.;† Yu, S.; Sheng, T.; Ma, H.-B.; Chen, L.-N.; Rauf, M.; Xia, H.-P.; Zhou, Z.-Y.;* Sun, S.-G. Constructing Canopy-Shaped Molecular Architectures to Create Local Pt Surface Sites with High Tolerance to H2S and CO for Hydrogen Electrooxidation. Energy Environ. Sci. 2018, 11, 166-171.(†Wang and Chen contributed equally to this work.)
81. Lu, Z.; Cai, Y.; Wei, Y; Lin, Q.; Chen, J.;* He, X.; Li, S.; Wu, W.; Xia, H.* Photothermal Möbius Aromatic Metallapentalenofuran and Its NIR-Responsive Copolymer. Polym. Chem. 2018, 9, 2092-2100. (Cover Paper)
80. Chen, J.;* Lin, Q.; Li, S.; Lu, Z; Lin, J.; Chen, Z.; Xia, H.* Synthesis and Characterization of an Osmapentalene Derivative Containing a β-Agostic Os···H–C(sp3) Interaction. Organometallics 2018, 37, 618-623.
79. Zhu, C.; Zhu, J.; Zhou, X.; Zhu, Q.; Yang, Y.; Wen, T. B.; Xia, H.* Isolation of an Eleven‐Atom Polydentate Carbon‐Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne. Angew. Chem., Int. Ed. 2018, 57, 3154-3157. (VIP Paper)
78. Zhou, X.; Zhang, H.* Reactions of Metal-Carbon Bonds within Six-Membered Metallaaromatic Rings. Chem. - Eur. J. 2018, 24, 8962-8973.
77. Hua, Y.; Zhang, H.;* Xia, H.* Aromaticity: History and Development. Chin. J. Org. Chem. 2018, 38, 11-28.
76. Wang, H.;† Zhou, X.;† Xia, H.* Metallaaromatics Containing Main‐Group Heteroatoms. Chin. J. Chem. 2018, 36, 93-105.(†Wang and Zhou contributed equally to this work.)
75. Zhou, X.; Wu, J.; Hao, Y.; Zhu, C.; Zhuo, Q.; Xia, H.;* Zhu, J.* Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity. Chem. - Eur. J. 2018, 24, 2389-2395. (Cover Paper)
74. Yang, C.;† Lin, G.;† Zhu, C.;† Pang, X.; Zhang, Y.; Wang, X.; Li, X.; Wang, B.;* Xia, H.;* Liu, G.* Metalla-Aromatic Loaded Magnetic Nanoparticles for MRI/Photoacoustic Imaging-Guided Cancer Phototherapy. J. Mater. Chem. B 2018, 6, 2528-2535. (Frontispiece Paper)(†Yang, Lin and Zhu contributed equally to this work.)
73. Huang, J.; Zhou, X.; Zhao, Q.; Li, S.; Xia, H.* Synthesis, Characterization and Electrochemical Properties of 4,5-Diazafluoren-9-yl or Fluoren-9-yl Terminated Homobimetallic Ruthenium and Osmium Allenylidene, Alkynyl-Allenylidene Complexes. Chin. J. Chem. 2017, 35, 420-428.
72. Zhuo, Q.; Lin, J.; Hua, Y.; Zhou, X.; Shao, Y.; Chen, S.; Chen, Z.; Zhu, J.; Zhang, H.; Xia, H.* Multiyne Chains Chelating Osmium via Three Metalcarbon σ Bonds. Nat. Commun. 2017, 8, 1912.
71. Huang, Z.-A.; Lan, Q.; Hua, Y.; Chen, Z.; Zhang, H.;* Lin, Z.; Xia, H. Color-Tuning Strategy for Iridapolycycles [(N∧N)Ir(C∧C)ClPPh3]+ by the Synergistic Modifications on Both the C∧C and N∧N Units. Organometallics 2017, 36, 4802–4809.
70. Long, L.; Zhou, X.; Wang, T.; Chen, Z.; Zhang, H.;* Xia, H.* Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine. Organometallics 2017, 36, 4184−4190.
69. Li, R.;† Lu, Z.;† Cai, Y.; Jiang, F.; Tang, C.; Chen, Z.; Zheng, J.; Pi, J.; Zhang, R.; Liu, J.; Chen, Z.; Yang, Y.; Shi, J.; Hong, W.;* Xia, H.* Switching of Charge Transport Pathways via Delocalization Changes in Single-Molecule Metallacycles Junctions. J. Am. Chem. Soc. 2017, 139, 14344-14347. (Inside Cover Paper)(†Li and Lu contributed equally to this work.)
68. He, X.;* He, X.; Li, S.; Zhuo, K.; Qin, W.; Dong, S.; Chen, J.; Ren, L.; Liu, G.; Xia, H.* Amphipathic Metal-containing Macromolecules with Photothermal Properties. Polym. Chem. 2017, 8, 3674-3678.(Inside Cover Paper)
67. Zhu, C.; Wu, J.; Li, S.; Yang, Y.; Zhu, J.; Lu, X.; Xia, H.* Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-Membered Rings. Angew. Chem., Int. Ed. 2017, 56, 9067-9071.
66. Lu, Z.; Chen, J.; Xia, H.* Synthesis of Olefinic Carbolong Complexes. Chin. J. Org. Chem. 2017, 37, 1181-1188.
65. Lu, Z.;† Zhu, C.;† Cai, Y.; Zhu, J.; Hua, Y.; Chen, Z.; Chen, J.;* Xia, H.* Metallapentalenofurans and Lactone-Fused Metallapentalynes. Chem. - Eur. J. 2017, 23, 6426-6431.(†Lu and Zhu contributed equally to this work.)
64. Luo, M.; Long, L.; Zhang, H.;* Yang, Y.; Hua, Y.; Liu, G.; Lin, Z.;* Xia, H.* Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates. J. Am. Chem. Soc. 2017,139, 1822-1825.
63. Zhu, Q.; Zhu, C.; Deng, Z.; He, G.;* Chen, J.; Zhu, J.; Xia, H.* Synthesis and Characterization of Osmium Polycyclic Aromatic Complexes via Nucleophilic Reactions of Osmapentalyne. Chin. J. Chem. 2017, 35, 628-634.
62. Zhu, C.;† Yang, C.;† Wang, Y.; Lin, G.; Yang, Y.; Wang, X.; Zhu, J.; Chen, X.; Lu, X.;* Liu, G.;* Xia, H.* CCCCC Pentadentate Chelates with Planar Möbius Aromaticity and Unique Properties. Sci. Adv. 2016, 2, e1601031.(†Zhu and Yang contributed equally to this work.) This article has been highlighted by: C & EN, PhysOrg, NSFC.
61. Chen, J.;† Huang, Z.-A.;† Lu, Z.; Zhang, H.;* Xia, H.* Synthesis of Cyclic Vinylidene Complexes and Azavinylidene Complexes by Formal [4+2] Cyclization Reactions. Chem. - Eur. J. 2016, 22, 5363-5375.(†Chen and Huang contributed equally to this work.)
60. Zhuo, Q.; Zhou, X.; Kang, H.; Chen, Z.; Yang, Y.; Han, F.; Zhang, H.;* Xia, H.* Synthesis of Fused Metallaaromatics via Intramolecular C−H Activation of Thiophenes. Organometallics 2016, 35, 1497-1504.
59. Zhuo, Q.;† Chen, Z.;† Yang, Y.; Zhou, X.; Han, F.; Zhu, J.; Zhang, H.;* Xia, H.* Synthesis of Aromatic Ruthenabenzothiophenes via C–H Activation of Thiophenes. Dalton Trans. 2016, 45, 913-917.(†Zhuo and Chen contributed equally to this work.)
58. Luo, M.; Zhu, C.; Chen, L.; Zhang, H.;* Xia, H.* Halogenation of Carbyne Complexes: Isolation of Unsaturated Metallaiodirenium Ion and Metallabromirenium Ion. Chem. Sci. 2016, 7, 1815-1818.
57. Xu, H.;† Huang, Z.-A.;† Guo, X.; Yang, Y.; Hua, Y.; Cao, Z.; Li, S.;* Xia, H.* Sequential Construction Strategy for Rational Design of Luminescent Iridacycles. Organometallics 2015, 34, 4229-4237.(†Xu and Huang contributed equally to this work.)
56. Zhou, X.; He, X.; Lin, J.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Wang, J.; Xia, H.* Reactions of Osmium Hydrido Alkenylcarbyne with Allenoates: Insertion and [3 + 2] Annulation. Organometallics 2015, 34, 1742-1750.
55. Zhu, C.; Yang, Y.; Wu, J.; Luo, M.; Fan, J.; Zhu, J.;* Xia, H.* Five-Membered Cyclic Metal Carbyne: Synthesis of Osmapentalynes by the Reactions of Osmapentalene with Allene, Alkyne, and Alkene. Angew. Chem., Int. Ed. 2015, 54, 7189-7192.
54. Wang, T.; Han, F.; Huang, H.; Li, J.; Zhang, H.;* Zhu, J.; Lin, Z.;* Xia, H.* Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation. Sci. Rep. 2015, 5, 9584.
53. Wei, Y.; Zhou, X.; Hong, G.; Chen, Z.; Zhang, H.;* Xia, H.* Reactions of Osmapyridinium with Terminal Alkynes. Org. Chem. Front. 2015, 2, 560-568.
52. Zhu, C.; Yang, Y.; Luo, M.; Yang, C.; Wu, J.; Chen, L.; Liu, G.; Wen, T.; Zhu, J.;* Xia, H.* Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics. Angew. Chem., Int. Ed. 2015, 54, 6181-6185.
51. Xu, H.; Xu, Y.; Pang, X.; He, Y.; Jung, J.; Xia, H.;* Lin, Z.* A General Route to Nanocrystal Kebabs Periodically Assembled on Stretched Flexible Polymer Shish. Sci. Adv. 2015, 1, e1500025.
This article has been highlighted by: Scienceshot, Sciences, Georgia Institute of Technology, PhysOrg, ScienceDaily, Nanowerk, World of Chemicals, Nanotechnology Now, Pinterest, Fnews, Nano Daily, TrendsSoul.
50. Xu, H.; Pang, X.; He, Y.; He, M.; Jung, J.; Xia, H.;* Lin, Z.* An Unconventional Route to Monodisperse and Intimately Contacted Semiconducting Organic–Inorganic Nanocomposites. Angew. Chem., Int. Ed. 2015, 54, 4636-4640.(Inside Cover)
49. Zhu, C.; Zhou, X.; Xing, H.; An, K.; Zhu, J.;* Xia, H.* σ-Aromaticity in an Unsaturated Ring: Osmapentalene Derivatives Containing a Metallacyclopropene Unit. Angew. Chem., Int. Ed. 2015, 54, 3102-3106.
48. Han, F.; Li, J.; Zhang, H.;* Wang, T.; Lin, Z.;* Xia, H.* Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene. Chem. - Eur. J. 2015, 21, 565-567.
47. Chen, J.;† Huang, Z.-A.;† Hua, Y.; Zhang, H.;* Xia, H. Synthesis of Five-Membered Osmacycles with Osmium–Vinyl Bonds from Hydrido Alkenylcarbyne Complexes. Organometallics 2015, 34, 340-347.(†Chen and Huang contributed equally to this work.)
46. Lin, Z.;* Zhu, C.; Xia, H. HRMS Studies on the Fragmentation Pathways of Metallapentalyne. Spectrochim. Acta, Part A 2015, 136, 906-910.
45. Wang, X.; Zhu, C.; Xia, H.;* Zhu, J.* Theoretical Study on the Stability and Aromaticity of Metallasilapentalynes. Organometallics 2014, 33, 1845-1850.
44. Han, F.; Wang, T.; Li, J.; Zhang, H.; Zhang, L.; He, X.;* Xia, H.* Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex. Organometallics 2014, 33, 5301-5307.
43. Zhang, H.;* Lin, R.; Li, J.; Zhu, J.; Xia, H. Interconversion between Ruthenacyclohexadiene and Ruthenabenzene: A Combined Experimental and Theoretical Study. Organometallics 2014, 33, 5606-5609.
42. Zhou, X.; Zhang, C.; Lin, Y.; He, X.; Zhang, Y.; Wang, J.; Xia, H.* 1,2-Migration in the Reactions of Ruthenium Vinylcarbene with Propargyl Alcohols. Org. Chem. Front. 2014, 1, 1077-1082.
41. Zhuo, Q.; Wang, T.; Zhou, X.; Zhang, H.* Progresses of Ring Expansion Reaction of Small Transitional Metallacyclic Compounds. Chin. J. Org. Chem. 2014, 34, 1471-1486.
40. Han, F.; Wang, T.; Li, J.; Zhang, H.;* Xia, H.* m-Metallaphenol: Synthesis and Reactivity Studies. Chem. - Eur. J. 2014, 20, 4363-4372.(Cover Paper)
39. Zhu, C.; Zhu, Q.; Fan, J.; Zhu, J.; He, X.; Cao, X.-Y.;* Xia, H.* A Metal-Bridged Tricyclic Aromatic System: Synthesis of Osmium Polycyclic Aromatic Complexes. Angew. Chem., Int. Ed. 2014,53, 6232-6236.
38. Zhu, C.; Luo, M.; Zhu, Q.; Zhu, J.;* Schleyer, P. v. R.; Wu, J. I.-C.; Lu, X.; Xia, H.* Planar Möbius Aromatic Pentalenes Incorporating 16 and 18 Valence Electron Osmiums. Nat. Commun. 2014, 5, 3265.
37. Cao, X.-Y.; Zhao, Q.; Lin, Z.;* Xia, H.* The Chemistry of Aromatic Osmacycles. Acc. Chem. Res. 2014, 47, 341-354.
36. Wang, T.; Zhu, J.; Han, F.; Zhou, C.; Chen, H.; Zhang, H.;* Xia, H.* Synthesis of Five‐Membered Osmacycloallenes and Conversion into Six‐Membered Osmacycloallenes. Angew. Chem., Int. Ed. 2013, 52, 13361-13364.
35. Wang, T.;† Zhang, H.;† Han, F.; Long, L.; Lin, Z.;* Xia, H.* Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization. Angew. Chem., Int. Ed. 2013, 52, 9251-9255.(†Wang and Zhang contributed equally to this work.)
34. Zhu, C.; Li, S.; Luo, M.; Zhou, X.; Niu, Y.; Lin, M.; Zhu, J.;* Cao, Z.; Lu, X.; Wen, T.; Xie, Z.; Schleyer, P. v. R.; Xia, H.* Stabilization of Anti-aromatic and Strained Five-Membered Rings with a Transition Metal. Nat. Chem. 2013, 5, 698–703.
德国化学家Uwe Rosenthal教授等在同期《Nature Chemistry》的“News and Views”栏目以《Metallacycles: Breaking the rules》为题撰文评述了这一研究成果（Nat. Chem., 2013, 5, 649-650）。
美国化学会 “Noteworthy Chemistry” 2013年8月5日以“Metallacycles show rare Möbius aromaticity” 为题专题评述这一研究成果。
“Nature China” 2013年8月7日以“Unusual aromatics”为题专题评述这一研究成果。
1981年诺贝尔化学奖获得者、美国康奈尔大学Roald Hoffmann教授在邮件中评价该项工作说：'The paper is an excellent one -- it's quite amazing that the parent Os system, molecule 1, chooses to give the osmapentalyne'，邮件最后说'You can use my name as someone you showed the paper to'。
33. Chen, J.; Zhang, C.; Xie, T.; Wen, T. B.; Zhang, H.;* Xia, H.* Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes. Organometallics 2013, 32, 3993-4001.
32. Zhang, C.; Zhang, H.; Zhang, L.; Wen, T. B.; He, X.;* Xia, H.* Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization. Organometallics 2013, 32, 3738-3743.
31. Wang, T.;† Zhang, H.;† Han, F.; Long, L.; Lin, Z.;* Xia, H.* cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study. Chem. - Eur. J. 2013, 19, 10982-10991.(†Wang and Zhang contributed equally to this work.)
30. Niu, Y.; Han, F.; Zhang, Q.; Xie, T.; Lu, L.; Li, S.;* Xia, H.* Off/On Fluorescent Chemosensors for Organotin Halides Based on Binuclear Ruthenium Complexes. Angew. Chem., Int. Ed. 2013, 52, 5599-5603.
29. Zhu, C.; Cao, X.;* Xia, H.* Double Stabilization of Highly Strained Six-Membered Rings by Phosphonium and Transition Metal. Chin. J. Org. Chem. 2013, 33, 657-662.（Invited and Cover Paper)
28. Zhao, Q.; Cao, X.-Y.;* Wen, T. B.; Xia, H.* From Osmium Hydrido Vinylidene to Osmacycles: The Key Role of Osmabutadiene Intermediates. Chem. - Asian J. 2013, 8, 269-275.
27. Wang, T.;† Zhang, H.;† Han, F.; Lin, R.; Lin, Z.;* Xia, H.* Synthesis and Characterization of a Metallapyridyne Complex. Angew. Chem., Int. Ed. 2012, 51, 9838-9841.(†Wang and Zhang contributed equally to this work.)
26. Zhao, Q.; Zhu, J.; Huang, Z.-A.; Cao, X.-Y.;* Xia, H.* Conversions of Osmabenzyne and Isoosmabenzene. Chem. - Eur. J. 2012, 18, 11597-11603.(Inside Cover Paper)
25. Lin, R.; Zhao, J.; Chen, H.; Zhang, H.;* Xia, H.* Interconversion of Metallabenzenes and Cyclic η2-Allene-Coordinated Complexes. Chem. - Asian J. 2012, 7, 1915-1924.
24. Zhao, Q.; Gong, L.; Xu, C.; Zhu, J.;* He, X.; Xia, H.* Stable Iso-osmabenzenes from a Formal [3+3] Cycloaddition Reaction of Metal Vinylidene with Alkynols. Angew. Chem., Int. Ed. 2011, 50, 1354–1358.
23. Lin, R.; Zhang, H.;* Li, S.; Wang, J.; Xia, H.* New Highly Stable Metallabenzenes via Nucleophilic Aromatic Substitution Reaction. Chem. - Eur. J. 2011, 17, 4223–4231.(Inside Cover Paper)
22. Lin, R.; Zhang, H.; Li, S.;* Chen, L.; Zhang, W.; Wen, T. B.; Zhang, H.; Xia, H.* pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene with L- and D-Cysteine. Chem. - Eur. J. 2011, 17, 2420–2427. 2011年2月28日美国化学会网页“Noteworthy Chemistry”栏目针对本文发表点评。
21. Zhang, H.;* Lin, R.; Hong, G.; Wang, T.; Wen, T. B.; Xia, H.* Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes. Chem. - Eur. J. 2010, 16, 6999–7007.
20. He, X.; Gong, L.; Kräling, K.; Gründler, K.; Frias, C.; Webster, R. D.; Meggers, E.;* Prokop, A.;* Xia, H.* Unusual η2-Allene Osmacycle with Apoptotic Properties, ChemBioChem 2010, 11, 1607-1613.
19. Zhang, H.;* Lin, R.; Luo, M.; Xia, H.* Synthesis and Characterization of Stable Osmafuran Starting from HC≡CCH(OH)C≡CH and OsHCl(CO)(PPh3)3. Sci. China: Chem. 2010, 53, 1978–1981.
18. He, X.-M.;* Liu, Q.; Gong, L.; Lin, Y.; Wen, T. B.* Synthesis of an Osmafuran from Photochemical Hydrolysis of OsCl2(CH=C(PPh3)C(O)-η2-CH=CH2)(PPh3)2. Inorg. Chem. Commun. 2010, 13, 342–345.
17. Huang, J.; Lin, R.; Wu, L.; Zhao, Q.; Zhu, C.; Wen, T. B.;* Xia, H.* Synthesis, Characterization, and Electrochemical Properties of Bisosmabenzenes Bridged by Diisocyanides. Organometallics 2010, 29, 2916–2925.
16. Lin, Y.; Xu, H.; Gong, L.; Wen, T. B.; He, X.-M.;* Xia, H.* C-H Bond Activation and Subsequent C(sp(2))-C(sp(3)) Bond Formation: Coupling of Bromomethyl and Triphenylphosphine in an Iridium Complex. Organometallics 2010, 29, 2904–2910.
15. Liu, B.; Wang, H.; Xie, H.; Zeng, B.; Chen, J.; Tao, J.; Wen, T. B.; Cao, Z.; Xia, H.* Osmapyridine and Osmapyridinium from a Formal [4+2] Cycloaddition Reaction. Angew. Chem., Int. Ed. 2009, 48, 5430–5434.本文为该杂志的VIP（Very Important Paper）和 Frontispiece Paper。英国皇家化学会的“Chemistry Word”2009年4月14日针对本文发表了题为“锇和吡啶环在一起”的报道。文章首句写到：中国有机化学家发现了一种把金属锇放到吡啶环中的方法。该报道被多家韩、俄文科技媒体转载。
14. Wang, T.; Li, S.; Zhang, H.; Lin, R.; Han, F.; Lin, Y.; Wen, T. B.; Xia, H.* Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole. Angew. Chem., Int. Ed. 2009, 48, 6453–6456.
13. Liu, B.; Xie, H.; Wang, H.; Wu, L.; Zhao, Q.; Chen, J.; Wen, T. B.; Cao, Z.;* Xia, H.* Selective Synthesis of Osmanaphthalene and Osmanaphthalyne by Intramolecular C-H Activation. Angew. Chem., Int. Ed. 2009, 48, 5461–5464.
12. Gong, L.; Chen, Z.; Lin, Y.; He, X.;* Wen, T. B.; Xu, X.; Xia, H.* Osmabenzenes from Osmacycles Containing an η2-Coordinated Olefin. Chem. - Eur. J. 2009, 15, 6258–6266.
11. Zhang, H.; Wu, L.; Lin, R.; Zhao, Q.; He, G.; Yang, F.; Wen, T. B.; Xia, H.* Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3 Substituents. Chem. - Eur. J. 2009, 15, 3546–3559.
10. Lin, Y.; Gong, L.; Xu, H.; He, X.; Wen, T. B.; Xia, H.* Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran. Organometallics 2009, 28, 1524–1533.
9. Gong, L.; Lin, Y.; Wen, T. B.;* Xia, H.* Synthesis of Coordinated η2-α,β-Unsaturated Ketone Osmacycles from an Osmium-Coordinated Alkyne Alcohol Complex. Organometallics 2009, 28, 1101–1111.
8. Wu, L.; Feng, L.; Zhang, H.; Liu, Q.; He, X.; Yang, F.; Xia, H.* Synthesis and Characterization of a Novel Dialdehyde and Cyclic Anhydride. J. Org. Chem. 2008, 73, 2883–2885.
7. Gong, L.; Lin, Y.; Wen, T. B.; Zhang, H.; Zeng, B.; Xia, H.* Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction. Organometallics 2008, 27, 2584–2589.
6. Gong, L.; Lin, Y.; He, G.; Zhang, H.; Wang, H.; Wen, T. B.;* Xia, H.* Synthesis and Characterization of an Air-Stable p-Osmaphenol. Organometallics 2008, 27, 309–311.
5. Gong, L.; Wu, L.; Lin, Y.; Zhang, H.; Yang, F.; Wen, T.; Xia, H.* Synthesis and Characterization of a Bimetallic Iridium Complex with a Ten sp2-Carbon Chain Bridge. Dalton Trans. 2007, 4122–4125. (Hot Article)
4. Zhang, H.; Feng, L.; Gong, L.; Wu, L.; He, G.; Wen, T.; Yang, F.; Xia, H.* Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC≡CCH(OH)C≡CH. Organometallics 2007, 26, 2705–2713.
3. Zhang, H.; Xia, H.;* He, G.; Wen, T. B.; Gong, L.; Jia, G.* Synthesis and Characterization of Stable Ruthenabenzenes. Angew. Chem., Int. Ed. 2006, 45, 2920–2923. 本文为该杂志的“VIP（Very Important Paper）”。美国化学会网页“Heart Cut” 栏目2006年5月30日针对本文发表题为 “现在你可以制备稳定的钌苯了”的评论。
2. Xia, H.;* He, G.; Zhang, H.; Wen, T. B.; Sung, H. H. Y.; Williams, I. D.; Jia, G.* Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3 (X = Cl, Br). J. Am. Chem. Soc. 2004, 126, 6862–6863. 美国化学会的“Chemical & Engineering News”, 82(23), 30（2004年6月7日）针对本文发表题为“锇苯很容易做”的报道。
1. He, G.; Xia, H.;* Jia, G. Progress in the Synthesis and Reactivity Studies of Metallabenzenes. Chin. Sci. Bull. 2004, 49, 1543–1553.