近期发表的主要研究论文：

71. Zhao, J.; Cai, Y.; Yang, X.; Zhang, H.* Heavier Group 14 Congeners of Metalla-isobenzenes: Access to Metalla-isosilabenzene and Metalla-isogermabenzene by One-Pot Reactions. Chin. J. Chem. 2024, 42, 1121-1127.

70. Lin, Z.; Yan, Z.; Cai, Y.; Xuan, J.; He, N.; Zhang, H.* Reactions of Ruthenabenzene with Propynols Involving Hydrogen-Bonding-Induced [2 + 2] Cycloaddition. Organometallics. 2023. 42, 1615−1620

69. Lin, Z.;† Cai, Y.;† Zhang, Y.; Zhang, H.;* Xia, H.* Heterocyclic Suzuki–Miyaura coupling reaction of metalla-aromatics and mechanistic analysis of site selectivity. Chem. Sci. 2023,14, 1227-1233.(Lin and Cai contributed equally to this work.)

68. Huang, F.; Yan, Z.; Zheng, X.; Cai, Y.; Zhang, H.;* Xia, H.* One-pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne. Chem. - Eur. J. 2022, 28, e202201229.

67. Zhang, H.;* Thogersen, M. K.; Jamieson, C. S.; Xue, X.-S.; Jorgensen, K. A.;* Houk, K.* Ambimodal Transition States in Diels-Alder Cycloadditions of Tropolone and Tropolonate with N-Methylmaleimide. Angew. Chem. Int. Ed. 2021, 60, 24991-24996.

66. Cai, Y.;† Hua, Y.;† Lu, Z.; Lan, Q.; Lin, Z.; Fei, J.; Chen, Z.; Zhang, H.;* Xia, H.* Electrophilic aromatic substitution reactions of compounds with Craig-Mobius aromaticity. Proc. Natl. Acad. Sci. U. S. A. 2021, 118, e2102310118.(Cai and Hua contributed equally to this work.)

65. Zhang, H.;* Novak, A. J. E.; Jamieson, C. S.; Xue, X. S.; Chen, S.; Trauner, D.;* Houk, K. N.* Computational Exploration of the Mechanism of Critical Steps in the Biomimetic Synthesis of Preuisolactone A, and Discovery of New Ambimodal (5 + 2)/(4 + 2) Cycloadditions. J. Am. Chem. Soc. 2021, 143, 6601-6608.

64. Luo, M.;† Cai, Y.;† Lin, X.; Long, L.; Zhang, H.;* Xia, H.* Synthesis, Characterization and Reactivity of Metalla-chalcogenirenium Compounds. Chin. J. Chem. 2021, 39, 1558-1564.(Luo and Cai contributed equally to this work.)

63 .Zhang, J.-X.;† Sheong, F. K.;† Lu, Z.; Zhang, H.;* Lin, Z.* Unexpected Electronic Behavior of Organic Azide and Metal‐Carbyne in Their 1,3‐Dipolar Cycloaddition Reaction. Chin. J. Chem. 2020, 38, 1565-1570.(Zhang and Sheong contributed equally to this work.)

62. Huang, F.; Zheng, X.; Lin, X.; Ding, L.; Zhuo, Q.; Wen, T. B.; Zhang, H.;* Xia, H.* Extension of the Simmons–Smith Reaction to Metal-carbynes: Efficient Synthesis of Metallacyclopropenes with σ-Aromaticity. Chem. Sci. 2020, 11, 10159-10166.

61. Deng, Z.;† Wu, P.;† Cai, Y.; Sui, Y.; Chen, Z.; Zhang, H.; Wang, B.;* Xia, H.* Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations. iScience 2020, 23, 101379. (Deng and Wu contributed equally to this work.)

60. Lin, J.; Xu, Q.; Lin, X.; Hua, Y.; Chen, D.; Ruan, Y.; Zhang, H.;* Xia, H.* The First OCCCO Pentadentate Chelates: Osmium Mediated Stepwise Oxidations of Terminal Alkynes by Pyridine N‐Oxide. Chin. J. Chem. 2020, 38, 1273-1279.

59. Luo, M.; Hua, Y.; Zhuo, K.; Long, L.; Lin, X.; Deng, Z.; Lin, Z.; Zhang, H.; Chen, D.; Xia, H.* Carbolong Chemistry: Planar CCCCX-Type (X = N, O, S) Pentadentate Chelates by Formal [3+1] Cycloadditions of Metalla-Azirines with Terminal Alkynes. CCS Chemistry 2020, 2, 758-763.

58. Luo, M.; Sui, Y.; Lin, X.; Zhu, C.; Yan, Z.; Ruan, Y.; Zhang, H.;* Xia, H.* [3+2] Cycloaddition Reaction of Metallacyclopropene with Nitrosonium Ion: Isolation of Aromatic Metallaisoxazole. Chem. Commun. 2020, 56, 6806 - 6809.

57. Ni, D.; Witherspoon, B. P.; Zhang, H.; Zhou, C.; Houk, K. N.;* Brown, M. K.* Stereoselective [4+2]-Cycloaddition with Chiral Alkenylboranes. Angew. Chem., Int. Ed. 2020, 59, 11432-11439.

56. Lu, Z.;† Zhu, Q.;† Cai, Y.; Chen, Z.; Zhuo, K.; Zhu, J.; Zhang, H.;* Xia, H.* Access to Tetracyclic Aromatics with Bridgehead Metals via Metalla-click Reactions. Sci. Adv. 2020, 6, eaay2535.(Lu and Zhu contributed equally to this work.)

55. Zhuo, Q.;† Zhang, H.;† Ding, L.; Lin, J.; Zhou, X.; Hua, Y.; Zhu, J.; Xia, H.* Rhodapentalenes: Pincer Complexes with Internal Aromaticity. iScience 2019, 19, 1214-1224.(Zhuo and Zhang contributed equally to this work.)

54. Luo, M.; Deng, Z.; Ruan, Y.; Cai, Y.; Zhuo, K.; Zhang, H.;* Xia, H. Reactions of Metallacyclopentadiene with Terminal Alkynes: Isolation and Characterization of Metallafulvenallene Complexes. Organometallics 2019, 38, 3053-3059.(ACS Editors’ Choice)

53. Lin, J.; Ding, L.; Zhuo, Q.; Zhang, H.;* Xia, H.* Formal [2+2+2] Cycloaddition Reaction of a Metal–Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex. Organometallics 2019, 25, 5077-5085.

52. Zhou, X.; Pang, X.; Nie, L.; Zhu, C.; Zhuo, K.; Zhuo, Q.; Chen, Z.; Liu, G.; Zhang, H.;* Lin, Z.; Xia, H. Successive Modification of Polydentate Complexes Gives Access to Planar Carbon- and Nitrogen-based Ligands. Nat. Commun. 2019, 10, 1488.

51. Li, J.; Lin, Y. M.;* Zhang, H.; Chen, Y.; Lin, Z.; Xia, H.* Access to Metal-Bridged Osmathiazine Derivatives by a Formal [4+2] Cyclization. Chem. - Eur. J. 2019, 25, 5077-5085.

50. Li, J.; Kang, H.; Zhuo, K.; Zhuo, Q.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative. Chin. J. Chem. 2018, 36, 1156-1160.

49. Zhuo, Q.;† Zhang, H.;† Hua, Y.; Kang, H.; Zhou, X.; Lin, X.; Chen, Z.; Lin, J.; Zhuo, K.; Xia, H.* Constraint of a Ruthenium-Carbon Triple Bond to a Five-Membered Ring. Sci. Adv. 2018, 4 (6), eaat0336.(†Zhuo and Zhang contributed equally to this work.)

48. Zhou, X.; Li, Y.; Shao, Y.; Hua, Y.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes. Organometallics 2018, 37, 1788-1794.

47. Zhou, X.; Huang, F.; Tang, C.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Xia, H. A Missing Member of Conjugated N-Heterocycles: Realizing Pyrido[1,2-Α]azepine by Reacting Ruthenium Alkenylcarbene Complex with Alkyne. Chem. Commun. 2018, 54, 4009-4012.

46. Zhou, X.; Zhang, H.* Reactions of Metal-Carbon Bonds within Six-Membered Metallaaromatic Rings. Chem. - Eur. J. 2018, 24, 8962-8973.

45.  Hua, Y.; Zhang, H.;* Xia, H.* Aromaticity: History and Development. Chin. J. Org. Chem. 2018, 38, 11-28.

44. Zhuo, Q.; Lin, J.; Hua, Y.; Zhou, X.; Shao, Y.; Chen, S.; Chen, Z.; Zhu, J.; Zhang, H.; Xia, H.* Multiyne Chains Chelating Osmium via Three Metalcarbon σ Bonds. Nat. Commun. 2017, 8, 1912.

43. Long, L.; Zhou, X.; Wang, T.; Chen, Z.; Zhang, H.;* Xia, H.* Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine. Organometallics 2017, 36, 4184−4190.

42. Huang, Z.-A.; Lan, Q.; Hua, Y.; Chen, Z.; Zhang, H.;* Lin, Z.; Xia, H. Color-Tuning Strategy for Iridapolycycles [(N∧N)Ir(C∧C)ClPPh3]⁺ by the Synergistic Modifications on Both the C∧C and N∧N Units. Organometallics 2017, 36, 4802–4809.

41. Luo, M.; Long, L.; Zhang, H.;* Yang, Y.; Hua, Y.; Liu, G.; Lin, Z.;* Xia, H.* Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates. J. Am. Chem. Soc. 2017,139, 1822-1825.

40. Chen, J.;† Huang, Z.-A.;† Lu, Z.; Zhang, H.;* Xia, H.* Synthesis of Cyclic Vinylidene Complexes and Azavinylidene Complexes by Formal [4+2] Cyclization Reactions. Chem. - Eur. J. 2016, 22, 5363-5375.(†Chen and Huang contributed equally to this work.)

39. Zhuo, Q.; Zhou, X.; Kang, H.; Chen, Z.; Yang, Y.; Han, F.; Zhang, H.;* Xia, H.* Synthesis of Fused Metallaaromatics via Intramolecular C−H Activation of Thiophenes. Organometallics 2016, 35, 1497-1504.

38. Zhuo, Q.;† Chen, Z.;† Yang, Y.; Zhou, X.; Han, F.; Zhu, J.; Zhang, H.;* Xia, H.* Synthesis of Aromatic Ruthenabenzothiophenes via C–H Activation of Thiophenes. Dalton Trans. 2016, 45, 913-917.(†Zhuo and Chen contributed equally to this work.)

37. Luo, M.; Zhu, C.; Chen, L.; Zhang, H.;* Xia, H.* Halogenation of Carbyne Complexes: Isolation of Unsaturated Metallaiodirenium Ion and Metallabromirenium Ion. Chem. Sci. 2016, 7, 1815-1818.

36. Zhou, X.; He, X.; Lin, J.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Wang, J.;* Xia, H.* Reactions of Osmium Hydrido Alkenylcarbyne with Allenoates: Insertion and [3 + 2] Annulation. Organometallics 2015, 34, 1742-1750.

35. Wei, Y.; Zhou, X.; Hong, G.; Chen, Z.; Zhang, H.;* Xia, H.* Reactions of Osmapyridinium with Terminal Alkynes. Org. Chem. Front. 2015, 2, 560-568.

34. Chen, J.; Huang, Z.-A.; Hua, Y.; Zhang, H.;* Xia, H. Synthesis of Five-Membered Osmacycles with Osmium–Vinyl Bonds from Hydrido Alkenylcarbyne Complexes. Organometallics 2015, 34, 340-347.

33. Wang, T.; Han, F.; Huang, H.; Li, J.; Zhang, H.;* Zhu, J.; Lin, Z.;* Xia, H.* Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation. Sci. Rep. 2015, 5, 9584.

32. Han, F.; Li, J.; Zhang, H.;* Wang, T.; Lin, Z.;* Xia, H.* Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene. Chem. - Eur. J. 2015, 21, 565-567.

31. Chen, J.;† Huang, Z.-A.;† Hua, Y.; Zhang, H.;* Xia, H. Synthesis of Five-Membered Osmacycles with Osmium–Vinyl Bonds from Hydrido Alkenylcarbyne Complexes. Organometallics 2015, 34, 340-347.(†Chen and Huang contributed equally to this work.)

30. Han, F.; Wang, T.; Li, J.; Zhang, H.;* Xia, H.* m-Metallaphenol: Synthesis and Reactivity Studies. Chem. - Eur. J. 2014, 20, 4363-4372.

29. Zhang, H.;* Lin, R.; Li, J.; Xia, H. Interconversion between Ruthenacyclohexadiene and Ruthenabenzene: A Combined Experimental and Theoretical Study. Organometallics 2014, 33, 5606-5609.

28. Zhuo, Q.; Wang T.; Zhou, X.; Zhang, H.* Progresses of Ring Expansion Reaction of Small Transitional Metallacyclic Compounds. Chin. J. Org. Chem. 2014, 34, 1471-1486.

27. Han, F.; Wang, T.; Li, J.; Zhang, H.; Zhang; L.; He, X.;* Xia, H.* Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex. Organometallics 2014, 33, 5301-5307.

26. Wang, T.; Zhu, J.; Han, F.; Zhou, C.; Chen, H.; Zhang, H.;* Xia, H.* Synthesis of Five-membered Osmacycloallenes and Conversion to Six-membered Osmacycloallenes. Angew. Chem., Int. Ed. 2013, 52, 13361-13364.

25. Wang, T.;† Zhang, H.;† Han, F.; Long, L.; Lin, Z.;* Xia, H.* Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization. Angew. Chem., Int. Ed. 2013, 52, 9251-9255. (†Wang and Zhang contributed equally to this work.)

24. Wang, T.;† Zhang, H.;†  Han, F.; Long, L.; Lin, Z.;* Xia, H.* cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study. Chem. - Eur. J. 2013, 19, 10982-10991. (†Wang and Zhang contributed equally to this work.)

23. Chen, J.; Zhang, C.; Xie, T.; Wen, T. B.; Zhang, H.;* Xia, H. Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes. Organometallics 2013, 32, 3993-4001.

22. Zhang, C.; Zhang, H.; Zhang, L.; Wen, T. B.; He, X.;* Xia, H.* Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization. Organometallics 2013, 32, 3738-3743.

21. Zhang, C.; Zhang, H.; Wei, A.; He, X.;* Xia, H.* Synthesis of Ruthena-polycyclic Complexes by Ruthenium-Vinylcarbene Complex. Acta Chim. Sinica 2013, 71, 1373.

20. Xie, H.; Zhang, H.; Lin, Z.* DFT Studies on the Palladium-Catalyzed Dearomatization Reaction between Chloromethylnaphthalene and the Cyclic Amine Morpholine. Organometallics 2013, 32, 2336-2343.

19. Xie, H.; Zhang, H.; Lin, Z.* DFT Studies on the Mechanisms of Palladium-Catalyzed Intramolecular Arylation of a Silyl C(sp3)–H Bond. New J. Chem. 2013, 37, 2856-2861.

18. Wang, T.;† Zhang, H.;† Han, F.; Long, L.; Lin, Z.;* Xia, H.* Synthesis and Characterization of a Metallapyridyne Complex. Angew. Chem., Int. Ed. 2012, 51, 9838–9841. (†Wang and Zhang contributed equally to this work.)

17. Lin, R.; Zhao, J.; Chen, H.; Zhang, H.;* Xia, H.* Interconversion of Metallabenzenes and Cyclic η2-Allene-Coordinated Complexes. Chem. - Asian J. 2012, 7, 1915–1924.

16. Lin, R.; Zhang, H.;* Li, S.; Wang, J.; Xia, H.* New Highly Stable Metallabenzenes via Nucleophilic Aromatic Substitution Reaction. Chem. - Eur. J. 2011, 17, 4223–4231. (Inside Cover)

15. Lin, R.; Zhang, H.;* Cao, X.-Y.; Xia, H. The Electrophilic Aromatic Addition and Substitution Reactions of Metallabenzenes. Journal of Xiamen University(Natural Science) 2011, 50 (S1), 1-4.

14. Lin, R.; Zhang, H.; Li, S.*; Chen, L.; Zhang, W.; Wen, T. B.; Zhang, H.;* Xia, H.* pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene with l- and d-Cysteine. Chem. - Eur. J. 2011, 17, 2420-2427.(This article has been highlighted by ACS "Noteworthy Chemistry".)

13. Zhang, H.;* Lin, R.; Luo, M.; Xia, H.* Synthesis and Characterization of Stable Osmafuran Starting from HC≡CCH(OH)C≡CH and OsHCl(CO)(PPh3)3, Sci. China: Chem. 2010, 53, 1978-1981. 

12. Zhang, H.;* Lin, R.; Hong, G.; Wang, T.; Wen, T. B.; Xia, H.* Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes. Chem. - Eur. J. 2010, 16, 6999-7007.

11. Wang, T. ; Li, S.; Zhang H.; Lin R.; Han F.; Lin Y.; Wen T. B.; Xia, H.* Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole. Angew. Chem., Int. Ed. 2009, 48, 6453-6456.

10. Zhang, H.; Wu, L.; Lin, R.; Zhao, Q.; He, G.; Yang, F.; Wen, T. B.; Xia, H.* Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3 Substituents. Chem. - Eur. J. 2009, 15, 3546-3559.

9. Wu, L.; Feng, L.; Zhang, H.; Liu, Q.; He, X.; Yang, F.; Xia, H.* Synthesis and Characterization of a Novel Dialdehyde and Cyclic Anhydride. J. Org. Chem. 2008, 73, 2883–2885.

8. Gong, L.; Lin, Y.; Wen, T. B.; Zhang, H.; Zeng, B.; Xia, H.* Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction. Organometallics 2008, 27, 2584–2589.

7. Gong, L.; Lin, Y.; He, G.; Zhang, H.; Wang, H.; Wen, T. B.;* Xia, H.* Synthesis and Characterization of an Air-Stable p-Osmaphenol. Organometallics 2008, 27, 309–311.

6. Zhang, H.; Feng, L.; Gong, L.; Wu, L.; He, G.; Wen, T. B.; Yang, F.; Xia, H.* Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC≡CCH(OH)C≡CH. Organometallics 2007, 26, 2705-2713.

5. Gong, L.; Wu, L.; Lin, Y.; Zhang, H.; Yang, F.; Wen, T.; Xia, H.* Synthesis and Characterization of a Bimetallic Iridium Complex with a Ten sp²-Carbon Chain Bridge. Dalton Trans. 2007, 4122-4125.

4. Zhang, H.; Xia, H.;* He, G.; Wen, T. B.; Jia, G.* Synthesis and Characterization of Stable Ruthenabenzenes. Angew. Chem., Int. Ed. 2006, 45, 2920-2923.(VIP).（This article has been highlighted by ACS "Heart Cut".）

3. Xia, H.;* He, G.; Zhang, H.; Wen, T. B.; Sung, H. H. Y.; Williams, I. D.; Jia, G.* Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3 (X = Cl, Br). J. Am. Chem. Soc. 2004, 126, 6862-6863.（This article has been highlighted by ACS "Chemical & Engineering News". ）

2. Zhang, H.; He, G.; Xia, H.* Progress of Study on Linear Carbon Bridged Organometallic Molecular Wires. Chin. J. Org. Chem. 2004, 24, 355-365.

1. Zhang, H.; He, X.;* Ding, M. Application of Pessure-Driven Membrane in Meallurgical Industry. Journal of Functional Materials (Chinese) 2002, 33, 588-569, 593.