成员简介

张弘


个人简历:

1997.09-2001.07 厦门大学化学化工学院材料科学与工程系,学士
2001.09-2007.08 厦门大学化学化工学院化学系,博士
2007.08-2011.09 厦门大学化学化工学院化学系,助理教授
2012.04-2013.04 香港科技大学化学系,访问学者
2011.09-至今 厦门大学化学化工学院化学系,副教授


研究兴趣:

经典有机反应的拓展研究及导向有机合成的金属有机化学研究

联系方式:

厦门大学化学系卢嘉锡楼742室
Tel:0592-2184520
Email:zh@xmu.edu.cn

近期发表的主要研究论文:

46. Zhou, X.; Huang, F.; Tang, C.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Xia, H.; A missing member of conjugated N-heterocycles: realizing pyrido[1,2-α]azepine by reacting ruthenium alkenylcarbene complex with alkyne. Chem. Commun., 2018, 54, 4009 - 4012.
45. Zhou, X.; Zhang, H.; Reactions of Metal-Carbon Bonds within Six-MemberedMetallaaromatic Rings. Chem. Eur. J. 10.1002/chem.201705679.
44. Hua,Y.; Zhang, H.; Xia, H.. Youji Huaxue 2018, 38, 11.
43. Zhuo, Q.; Lin, J.; Hua, Y.; Zhou, X.; Shao, Y.; Chen, S.; Chen, Z.; Zhu, J.; Zhang, H.; Xia, H. Nat Commun 2017, 8, 1912.
42. Long, L.; Zhou, X.; Wang, T.; Chen, Z.; Zhang, H.; Xia, H. Organometallics 2017, 36, 4184.
41. Huang, Z.-A.; Lan, Q.; Hua, Y.; Chen, Z.; Zhang, H.; Lin, Z.; Xia, H. Organometallics 2017, 36, 4802.
40. Luo, M.; Long, L.; Zhang, H.; Yang, Y.; Hua, Y.; Liu, G.; Lin, Z.; Xia, H. J. Am. Chem. Soc. 2017, 139, 1822.
39. Chen, J.; Huang, Z.-A.; Lu, Z.; Zhang, H; Xia, H. Chem. Eur. J. 2016, 22, 5363-5375.
38. Zhuo, Q.; Zhou, X.; Kang, H.; Chen, Z.; Yang, Y.; Han, F.; Zhang, H.; Xia, H. Organometallics 2016, 35, 1497-1504.
37. Zhuo, Q.; Chen, Z.; Yang, Y.; Zhou, X.; Han, F.; Zhu, J.; Zhang, H.; Xia, H. Dalton Trans. 2016, 45, 913-917.
36. Luo, M.; Zhu, C.; Chen, L.; Zhang, H.; Xia, H. Chemical Science 2016, 7, 1815-1818.
35. Zhou, X.; He, X.; Lin, J.; Zhuo, Q.; Chen, Z.; Zhang, H.; Wang, J.; Xia, H. Organometallics 2015, 34, 1742.
34. Wei, Y.; Zhou, X.; Hong, G.; Chen, Z.; Zhang, H.; Xia, H. Organic Chemistry Frontiers 2015, 2, 560.
33. Wang, T.; Han, F.; Huang, H.; Li, J.; Zhang, H.; Zhu, J.; Lin, Z.; Xia, H. Sci. Rep. 2015, 5, 9584.
32. Han, F.; Li, J.; Zhang, H.; Wang, T.; Lin, Z.; Xia, H. Chem. Eur. J. 2015, 21, 565.
31. Chen, J.; Huang, Z.-A.; Hua, Y.; Zhang, H.; Xia, H. Organometallics 2015, 34, 340.
30. Han, F.; Wang, T.; Li, J.; Zhang, H.; Xia, H. Chem. Eur. J. 2014, 20, 4363.
29. Zhang, H.; Lin, R.; Li, J.; Zhu, J.; Xia, H. Organometallics 2014, 33, 5606.
28. Zhuo, Q.; Wang, T.; Zhou, X.; Zhang, H. Chin. J. Org. Chem. 2014, 34, 1471.
27. Han, F.; Wang, T.; Li, J.; Zhang, H.; Zhang, L.; He, X.; Xia, H. Organometallics 2014, 33, 5301.
26. Wang, T.; Zhu, J.; Han, F.; Zhou, C.; Chen, H.; Zhang, H.; Xia, H. Angew. Chem., Int. Ed. 2013, 52, 13361.
25. Wang, T.; Zhang, H.; Han, F.; Long, L.; Lin, Z.; Xia, H. Angew. Chem., Int. Ed. 2013, 52, 9251.
24. Wang, T.; Zhang, H.; Han, F.; Long, L.; Lin, Z.; Xia, H. Chem. Eur. J. 2013, 19, 10982.
23. Chen, J.; Zhang, C.; Xie, T.; Wen, T. B.; Zhang, H.; Xia, H. Organometallics 2013, 32, 3993.
22. Zhang, C.; Zhang, H.; Zhang, L.; Wen, T. B.; He, X.; Xia, H. Organometallics 2013, 32, 3738.
21. Zhang, C.; Zhang, H.; Wei, A.; He, X.; Xia, H. Acta Chim. Sinica 2013, 71, 1373.
20. Xie, H.; Zhang, H.; Lin, Z. Organometallics 2013, 32, 2336.
19. Xie, H.; Zhang, H.; Lin, Z. New J. Chem. 2013, 37, 2856.
18. Wang, T.; Zhang, H.; Han, F.; Lin, R.; Lin, Z.; Xia, H. Angew. Chem., Int. Ed. 2012, 51, 9838.
17. Lin, R.; Zhao, J.; Chen, H.; Zhang, H.; Xia, H. Chem. Asian J. 2012, 7, 1915.
16. Lin, R.; Zhang, H.; Li, S.; Wang, J.; Xia, H. Chem. Eur. J. 2011, 17, 4223.
15. Lin, R.; Zhang, H.; Cao, X.-Y.; Xia, H. Journal of Xiamen University(Natural Science) 2011, 50, 1.
14. Lin, R.; Zhang, H.; Li, S.; Chen, L.; Zhang, W.; Wen, T. B.; Zhang, H.; Xia, H. Chem. Eur. J. 2011, 17, 2420.
13. Zhang, H.; Lin, R.; Luo, M.; Xia, H. Sci. China Chem. 2010, 53, 1978.
12. Zhang, H.; Lin, R.; Hong, G.; Wang, T.; Wen, T. B.; Xia, H. Chem. Eur. J. 2010, 16, 6999.
11. Wang, T.; Li, S.; Zhang, H.; Lin, R.; Han, F.; Lin, Y.; Wen, T. B.; Xia, H. Angew. Chem., Int. Ed. 2009, 48, 6453.
10. Zhang, H.; Wu, L.; Lin, R.; Zhao, Q.; He, G.; Yang, F.; Wen, T. B.; Xia, H. Chem. Eur. J. 2009, 15, 3546.
9. Wu, L.; Feng, L.; Zhang, H.; Liu, Q.; He, X.; Yang, F.; Xia, H. J. Org. Chem. 2008, 73, 2883.
8. Gong, L.; Lin, Y.; Wen, T. B.; Zhang, H.; Zeng, B.; Xia, H. Organometallics 2008, 27, 2584.
7. Gong, L.; Lin, Y.; He, G.; Zhang, H.; Wang, H.; Wen, T. B.; Xia, H. Organometallics 2008, 27, 309.
6. Zhang, H.; Feng, L.; Gong, L.; Wu, L.; He, G.; Wen, T.; Yang, F.; Xia, H. Organometallics 2007, 26, 2705.
5. Gong, L.; Wu, L.; Lin, Y.; Zhang, H.; Yang, F.; Wen, T.; Xia, H. Dalton Trans. 2007, 4122.
4. Zhang, H.; Xia, H.; He, G.; Wen, T. B.; Gong, L.; Jia, G. Angew. Chem., Int. Ed. 2006, 45, 2920.
3. Xia, H.; He, G.; Zhang, H.; Wen, T. B.; Sung, H. H. Y.; Williams, I. D.; Jia, G. J. Am. Chem. Soc. 2004, 126, 6862.
2. Zhang, H.; He, G.; Xia, H. Chin. J. Org. Chem. 2004, 24, 355.
1. Zhang, H.; He, X.; Ding, M. Journal of Functional Materials 2002, 33, 588.

何旭敏

何旭敏:博士,教授。1965年出生,1985年7月厦门大学化学系本科毕业,之后留校任教,1990年7月获厦门大学理学硕士学位。1995-1999年在香港浸会大学从事访问研究,期间转而攻读博士学位,并于1998年11月获香港浸会大学博士学位。2001年晋升副教授,2009年晋升教授。1987年开始从事功能高分子的合成及膜分离过程研究,近年来涉足金属有机化学领域的研究,共发表论文70余篇。已主持福建省科技项目、福建省青年科技人才创新项目和厦门市科技项目等,并参加了多项科研合作项目,包括:国家自然科学基金面上项目、教育部重点科技项目、国家"九五"攻关专题、云南省省院省校科技项目、福建省重点科技项目、教育部骨干教师基金、建设部科技项目等。获省级、副省级、市级科技进步一、二等奖共5项:2004年获福建省科学技术二等奖和厦门市科技进步一等奖(副省级),排名第七;2001年获福建省科学技术二等奖,排名第三;2001年获福建省建设系统科技进步二等奖(市级),排名第五;2000年获厦门市科技进步二等奖(副省级),排名第三。

联系方式:

Email: hejin@xmu.edu.cn

近期发表的主要研究论文:

17. Zhang, C.; Zhang, H.; Zhang, L.; Wen, T. B.; He, X.;* Xia, H.* Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization. Organometallics 2013, 32, 3738-3743.

16. Xu, X.-X.; Zhou, C.-L.; Zeng, B.-R.;* Xia, H.-P.; Lan, W.-G.; He, X.-M.* Structure and properties of polyamidoamine/polyacrylonitrile composite nanofiltration membrane prepared by interfacial polymerization. Sep. Purif. Technol. 2012, 96, 229-236.

15. Zhao, Q.; Gong, L.; Xu, C.; Zhu, J.;* He, X.; Xia, H.* Stable Isoosmabenzenes from a Formal [3+3] Cycloaddition Reaction of Metal Vinylidene with Alkynols. Angew. Chem. Int. Ed. 2011, 50, 1354-1358.

14. He, X.; Gong, L.; Kräling, K.; Gründler, K.; Frias, C.; Webster, R. D.; Meggers, E.;* Prokop, A.;* Xia, H.* Unusual η2-Allene Osmacycle with Apoptotic Properties. ChemBioChem 2010, 11, 1607-1613.

13. Lin, Y.; Xu, H.; Gong, L.; Wen, T. B.; He, X.-M.;* Xia, H.* C-H Bond Activation and Subsequent C(sp2)-C(sp3) Bond Formation: Coupling of Bromomethyl and Triphenylphosphine in an Iridium Complex. Organometallics 2010, 29, 2904–2910.

12. Xiong, X.;* Duan, J.; Zou, W.; He, X.; Zheng, W. A pH-sensitive regenerated cellulose membrane. J. Membr. Sci. 2010, 363, 96–102.

11. Han Q.-R.; Wang B.-X.; Ding M.-T., He, X.-M.* Effect of Cu2+ upon the Fluorescent Properties of Dendrimer PAMAM-FCD. Chemical Journal of Chinese Universities (Chinese) 2010, 31, 181-185.

10. Gong, L.; Chen, Z.; Lin, Y.; He, X.;* Wen, T. B.; Xu, X.; Xia, H.* Osmabenzenes from Osmacycles Containing an η2-Coordinated Olefin. Chem. Eur. J. 2009, 15, 6258-6266.

9. He, X.-M.;* Xie, Q.-L.; Liu, J.; Lan, W.-G.; Xia, H.-P. Photocatalytic activity of size and phase selective TiO2 nanoparticles prepared by the membrane processing. Sep. Purif. Technol. 2009, 68, 153–158.

8. Xie, Q.-L.; Liu, J.; Xu, X.-X.; Han, G.-B.; Xia, H.-P.; He, X.-M.* Size Separation of Fe2O3 Nanoparticles via Membrane Processing. Sep. Purif. Technol. 2009, 66, 148-152.

7. Lin, Y.; Gong, L.; Xu, H.; He, X.; Wen, T. B.; Xia, H.*  Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran. Organometallics 2009, 28, 1524-1533.

6. Han Q.-R.; Wang B.-X.; He, X.-M.*; Ding M.-T., Xia H.-P. Synthesis and Fluorescent Properties of Dendrimer PAMAM(1G)-FCD. Chemical Journal of Chinese Universities (Chinese) 2009, 30, 629-631.

5. Me, X.-M.;* Xie, Q.-L.; Xia, H.-P.; Lan, W.-G. Application of Nanofiltration Process in 5′- GMP Production. Desalination 2008, 225, 322-328.

4. Wu, L.; Feng, L.; Zhang, H.; Liu, Q.; He, X.; Yang, F.; Xia, H.* Synthesis and Characterization of a Novel Dialdehyde and Cyclic Anhydride. J. Org. Chem. 2008, 73, 2883-2885.

3. He, X.-M.;* Yang P.-X.; Chen Z.-N.; Fu G.; Xu X.; Density Functional Method Studies on Configuration and Electronic Structure of R-ReO3. Chemical Journal of Chinese Universities (Chinese) 2008, 29, 2267-2272.

2. Huang, T. H.; Yu, Z. J.;* He, X. M.;* Huang, M. H.; Chen, L. F.; Xia, H. P.; Zhang, L. T. One-pot Synthesis and Characterization of a New, Branched Polycarbosilane Bearing Allyl Groups. Chin. Chem. Lett. 2007, 18, 754-757.

1. He, X. M.; Zheng, W.; Yang, P. X.; Xia, H. P.* 9-Anthracenecarboxaldehyde Functionalized Second Generation Poly(amidoamine) Dendrimers: Synthesis and Metal Absorption. Chin. Chem. Lett. 2006, 17, 1251-1254.

专利:

1. 一种XXXX的制备方法,国防专利,专利号:ZL 200710081727.7,第一发明人.
2. 纳米级TiO2水合物颗粒—水体系中离子脱除方法,发明专利,专利号:ZL 031030742,第一发明人.
3. 纳米级二氧化锆水合物颗粒—水体系中离子脱除方法,发明专利,专利号:ZL 200410055359.5,第二发明人.
教材:
1. 董炎明, 何旭敏. 高分子化学与物理习题汇编. 北京:科学出版社, 2013.
2. 何旭敏, 董炎明. 高分子化学学习指导. 北京: 科学出版社, 2007.
3. 何旭敏等. 悬浮聚合法制备聚乙烯苯及离子交换树脂的制备、表征和应用等二个实验. 见: 王尊本主编. 综合化学实验. 第二版. 北京: 科学出版社, 2007

林玉妹

林玉妹,博士,副教授

研究兴趣:

1) 金属杂芳香化合物的设计、合成与功能化研究
2 ) 金属纳米团簇的可控合成与性能开发

教育及工作经历:

2013.03-至今 厦门大学化学化工学院,副教授
2011.01-2012.09 德国马尔堡大学化学系,洪堡学者(导师:Stefanie Dehnen)
2010.10-2010.12 德国马尔堡大学化学系,博士后(导师:Stefanie Dehnen)
2005.09-2010.06 厦门大学化学化工学院,博士(导师:夏海平教授)
2001.09-2005.06 泉州师范学院,学士

代表性论文:

19. Guan, Z.-J.; Zeng, J.-L.; Nan, Z.-A.; Wan, X.-K.; Lin, Y.-M.;* Wang, Q.-M.* Thiacalix[4]arene: New Protection for Metal Nanoclusters. Sci. Adv. 2016, 2, e1600323.

18. Zeng, J.-L.; Guan, Z.-J.; Du,Y.; Nan, Z.-A.; Lin, Y.-M.;* Wang, Q.-M.* Chloride-Promoted Formation of a Bimetallic Nanocluster Au80Ag30 and the Total Structure Determination. J. Am. Chem. Soc. 2016, 138, 7848−7851.

17. Wang, J.-Y.; Liu, K.-G.; Guan, Z.-J.; Nan, Z.-A.; Lin, Y.-M.;* Wang, Q.-M.* [MnIIIMnIV2Mo14O56]17–: A Mixed-Valence Meso-Polyoxometalate Anion Encapsulated by a 64-Nuclearity Silver Cluster. Inorg. Chem. 2016, 55, 6833–6835.

16. Liu, K.-G.; Liu, X-Y.; Guan, Z.-J; Shi, K;* Lin, Y.-M.* Wang, Q.-M. The Transformation of Polyoxometalate in the Formation of  Intercluster Compound [Ag41(α-SiW10O37)(tBuC=C)27(CH3CN)3][β-SiW12O40]. Chem. Commun. 2016, 52, 3801-3804.

15. Wang, Q.-M.;* Lin, Y.-M.; Liu, K.-G. Role of Anions Associated with the Formation and Properties of Silver Clusters. Acc. Chem. Res., 2015, 48, 1570–1579.

14. Liu, K.-G.; Chen, S.-K.; Lin, Y.-M.;* Wang, Q.-M.* An Organic Anion Template: A 24-Nucleus Silver Cluster Encapsulating a Squarate Dimer. Chem. Commun., 2015, 51, 9896-9898.

13. Lin, Y.-M.;* Guan, Z-J; Liu, K.-G.; Jiang Z.-G.; Wang, Q.-M.,* Assembly of Silver Alkynyl Compounds with Various Nuclearities. Dalton Trans. 2015, 44, 2439-2446.

12. Jiang, Z.-G.; Shi, K.; Lin, Y.-M.;* Wang, Q.-M.* [Ag70(PW9O34)2(tBuC≡RC)44(H2O)2]8+: Ionothermal Synthesis of a Silver Cluster Encapsulating Lacunary Polyoxometalate Ions. Chem. Commu. 2014, 50, 2353-2355.

11. Zhou, X.; Zhang, C; Lin, Y.-M, He, X; Zhang, Y; Wang, J; Xia, H.* 1,2-Migration in the Reactions of Ruthenium Vinylcarbene with Propargyl Alcohols. Org. Chem. Front. 2014, 1, 1077-1082.

10. Lin, Y.-M.; Zhen, L.; Chang, S.-S.; Wang, Q.-M.* Directed formation of tri-connected Cu(I) coordination polymers, CrystEngComm. 2013, 15, 9372-9376.

9. Lin, Y.; Xie, D.; Massa, W. Dehnen, S.* Reversible Changes in Structural Dimensionality of Selenostannates in Ionic Liquids: Formation, Structures, Stability and Photocunductivity, Chem. Eur. J. 2013, 19, 8806-8813.

8. Lin, Y.; Massa, W. Dehnen, S.* “Zeoball” [Sn36Ge24Se132]24-: A Molecular Anion with Zeolite-Related Composition and Spherical Shape, J. Am. Chem. Soc. 2012, 134, 4497-4450.

7. Lin, Y.; Massa, W. Dehnen, S.* Controlling the Assembly of Chalcogenides Anions in Ionic Liquids: From Binary Ge/Se Through Ternary Ge/Sn/Se to Binary Sn/Se Frameworks, Chem. Eur. J. 2012, 18, 13427-13434.

6. Lin, Y.; Dehnen, S.* [BMIm]4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-framework Structure, Inorg. Chem. 2011, 50, 7913-7915.

5. Lin, Y.; Xu, H; Gong, L; Wen, T. B; He, X. M;* Xia, H.* C–H Bond Activation and Subsequent C(sp2)–C(sp3) Bond Formation : Coupling of Bromomethyl and Triphenylphosphine in an Iridium complex, Organometallics 2010, 29, 2904-2910.

4. Lin, Y.; Gong, L; Xu, H; He, XM; Wen, T. B; Xia, H.* Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran, Organometallics 2009, 28, 1524-1533.

3. Wang, T;  Li, S; Zhang, H; Lin, R; Han, F;  Lin, Y.;  Wen, T. B; Xia, H.* Annelation Reaction of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole, Angew. Chem. Int. Ed. 2009, 48, 6453-6456.

2. Gong, L; Chen, Z; Lin, Y.; He, X. M*; Wen, T. B; Xu, X; Xia, H.* Osmabenzenes from Osmacycles Containing an η2-Coordinated Olefin, Chem. Eur. J. 2009, 15, 6258-6266.

1. Gong, L; Lin, Y.; Wen, T. B*; Xia, H.* Synthesis of Coordinated η2-α,β-Unsaturated Ketone Osmacycles from an Osmium-coordinated Alkyne Alcohol Complex, Organometallics 2009, 28, 1101-1111.

陈江溪

工作经历:

2012/12-至今,厦门大学,材料学院材料科学与工程系,副教授
2008/07-2013/01,香港科技大学,化学系,博士后

教育经历:

2002/09-2007/10,厦门大学,高分子化学与物理专业,博士
1995/09-1999/07,厦门大学,材料化学专业,学士

研究领域:

1) 金属有机分子及其高分子材料的合成、制备与性能研究
2) 含金属的生物材料合成、制备与性能研究
3) 新型功能材料的开发与研究

主要代表学术论著与论文

14. He, X.;* He, X.; Li, S.; Zhuo, K.; Qin, W.; Dong, S.; Chen, J.; Ren, L.; Liu, G.; Xia, H.* Amphipathic Metal-containing Macromolecules with Photothermal Properties. Polym. Chem., 2017, 8, 3674-3678.

13. He, G.; Wu, L.; Bai, W.; Chen, J.;* Sung, H. H. Y.; Williams, I. D.; Lin, Z.;* Jia, G.* Synthesis and Reactivities of Polyhydrido Osmium Arylsilyl Complexes Prepared from OsH3Cl(PPh3)3, Organometallics 2017, 36, 3729-3738.

12. Lu, Z.; Zhu, C.; Cai, Y.; Zhu, J.; Hua, Y.; Chen, Z.; Chen, J.;* Xia, H.* Metallapentalenofurans and Lactone-Fused Metallapentalynes. Chem. Eur. J. 2017, 23, 6426-6431.

11. Chen, J.; Lee, K. H.; Sung, H. H.; Williams, I. D.;* Lin, Z.;* Jia, G.* Synthesis and Characterization of Dirhenadehydro[12]annulenes. Angew. Chem. Int. Ed. 2016, 55, 7194-7198.

10. Chen, J.; Lee, K.-H.; Wen, T.; Gao, F.; Sung, H. H. Y.; Williams, I. D.;* Lin, Z.;* Jia, G.* Rearrangement of Metallabenzynes to Chlorocyclopentadienyl Complexes. Organometallics 2015, 34, 890-896.

9. Chen J.; Jia G.* Recent Development in the Chemistry of Transition Metal-containing Metallabenzenes and Metallabenzynes, Coord. Chem. Rev. 2013, 257, 2491-2521.

8. 陈江溪,何国梅,贾国成*, 金属苯炔的合成与化学性质, 有机化学, 2013, 33, 792-798.

7. Chen, J.; Shi, C.; Sung, H. H.; Williams, I. D.; Lin, Z.;* Jia, G.* Synthesis and Characterization of Rhenabenzyne Complexes, Chem. Eur. J. 2012, 18, 14128-14139.

6. Chen, J.; Shi, C.; Sung, H. H.-Y.; Williams, I. D.; Lin, Z.;* Jia, G.* Hydrogen Shift Reactions of Rhenium Hydrido Carbyne Complexes, Organometallics 2012, 31, 1817-1824.

5. Chen, J.; Sung, H. H.; Williams, I. D.; Lin, Z.;*Jia, G.* Synthesis and Characterization of a Rhenabenzyne Complex. Angew. Chem. Int. Ed. 2011, 50, 10675-10678.

4. Chen, J.; Shi, C. ; Sung, H. H.; Williams, I. D., Lin, Z.* and Jia, G.* Conversion of Metallabenzynes into Carbene Complexes. Angew. Chem. Int. Ed. 2011, 50, 7295-7299.

3. Chen, J.; Sung, H. H.-Y.; Williams, I. D.; Jia, G.* Hydrolysis of Osmium and Ruthenium Carbyne Complexes. Organometallics 2011, 30, 6159-6165.

2. Chen, J.; He, G.; Sung, H. H.-Y.; Williams, I. D.; Lin, Z.; Jia, G.* Rhenium Carbyne and η2-Vinyl Complexes from One-Pot Reactions of ReH5(PMe2Ph)3 with Terminal Alkynes. Organometallics 2010, 29, 2693-2701.

1. Chen, J.; He, G.; Liao, Z.; Zeng, B.; Ye, J.; Chen, L.; Xia, H.;* Zhang, L. Control of structure formation of polycarbosilane synthesized from polydimethylsilane by Kumada rearrangement, J. Appl. Polym. Sci. 2008, 108, 3114-3121.

曹晓宇

曹晓宇:出生于福建龙岩,博士,副教授。

研究方向:

1) 金属杂芳香大共轭体系的设计、合成及其性能开发
2 ) 超分子化学:基于动态共价化学、金属络合和氢键作用力的自组装以及主客体化学
3 ) 新型共轭有机材料的设计、合成及其光电材料与生物应用

教育及工作经历:

2011.02-至今 厦门大学化学化工学院高分子研究所,副教授
2008.12-2011.02 荷兰埃因霍温理工大学生物医学与工程系,玛丽居里博士后(导师:E.W.(Bert)Meijer教授)
2004.09-2009.12 法国斯特拉斯堡大学超分子科学与工程研究所,博士(导师:Jean-Marie Lehn教授)
2003.07-2004.09 北京大学化学与分子工程学院,研究助理(导师:裴坚教授)
2001.12-2003.07 北京大学化学与分子工程学院,学士(导师:裴坚教授)
2000.12-2001.12 北京大学化学与分子工程学院,“莙政学者”(导师:席振峰教授)
1999.09-2000.12 清华大学化学系,研究见习(导师:赵玉芬教授)

代表性论文:

16. Cao, X.-Y.; Harrowfield, J.; Nitschke, J.; Ramírez, J.; Stadler, A.-M.; Kyritsakas-Gruber, N.; Madalan, A.; Rissanen, K.; Russo, L.; Vaughan, G.; Lehn, J.-M.* Generation of [2×2] Grid Metallosupramolecular Architectures from Preformed Ditopic Bis(acylhydrazone) Ligands and through Component Self-Assembly. Eur. J. Inorg. Chem., 2007, 2007, 2944-2965.

15. Zhou, Y.; Liu, W.-J.; Zhang, W.; Cao, X.-Y.; Zhou, Q.-F.; Ma, Y.-G.*; Pei, J.* Selective Oxidative Cyclization by FeCl3 in the Construction of 10H-Indeno[1,2-b]triphenylene Skeletons in Polycyclic Aromatic Hydrocarbons. J. Org. Chem. 2006, 71, 6822-6828.

14. Cao, X.-Y.; Zi, H.; Zhang, W.; Lu, H.; Pei, J.* Star-Shaped and Linear Nanosized Molecules Functionalized with Hexa-peri-hexabenzocoronene: Synthesis and Optical Properties. J. Org. Chem. 2005, 70, 3645-3653.

13. Zhang, W; Cao, X.-Y.; Zi, H.; Pei, J.* Single-Molecule Nanosized Polycyclic Aromatics with Alternant Five- and Six-Membered Rings: Synthesis and Optical Properties. Org. Lett. 2005, 7, 959-962.

12. Yu, G.; Cao, X.-Y.; Chen, C.; Zi, H.; Lu, H.; Lee, C.; Pei, J.* Novel Efficient Blue Light-Emitting Conjugated Polymers: Synthesis, Optical Properties, and Thermal Optical Stability. Proc. SPIE-Int. Soc. Opt. Eng. 2005, 5632 (Light-Emitting Diode Materials and Devices), 7-16.

11. Cao, X. Y.; Zhang, W.; Zi, H.; Pei, J.* π-Conjugated Twin Molecules Based on Truxene: Synthesis and Optical Properties. Org. Lett. 2004, 6, 4845-4848.

10. Cao, X.-Y.; Zhou, X.-H.; Zi, H.; Pei, J.* Novel Blue-Light-Emitting Truxene-Containing Hyperbranched and Zigzag Type Copolymers: Synthesis, Optical Properties, and Investigation of Thermal Spectral Stability. Macromolecules 2004, 37, 8874-8882.

9. Cao, X. Y.; Liu, X. H.; Zhou, X. H.; Zhang, Y.; Jiang, Y.; Cao, Y.; Cui, Y. X.; Pei, J.* Giant Extended π-Conjugated Dendrimers Containing the 10,15-Dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene Chromophore: Synthesis, NMR Behavior, Optical Properties, and Electroluminescence. J. Org. Chem. 2004, 69, 6050-6058.

8. Chen, Y.; Zhang, J.; Chen, J.; Cao, X. Y.; Wang, J.; Zhao, Y. F.* Sensitivity Improvement of Amino Acids by N-Terminal Diisopropyloxyphosphorylation in Electrospray Ionization Mass Spectrometry. Rapid Commun. Mass Spectrom. 2004, 18, 469-473.

7. Chen, H.; He, M.;* Cao, X.; Zhou, X.; Pei, J. Efficient Matrix-Assisted Laser Desorption/Ionization Method for Fully π-Conjugated Dendrimers. Rapid Commun. Mass Spectrom. 2004, 18, 367-370.

6. Cao, X. Y.; Zhang, W. B.; Wang, J. L.; Zhou, X. H.; Lu, H.; Pei, J.* Extended π-Conjugated Dendrimers Based on Truxene. J. Am. Chem. Soc. 2003, 125, 12430-12431.

5. Pei, J.;* Wang, J. L.; Cao, X. Y.; Zhou, X. H.; Zhang, W. B. Star-Shaped Polycyclic Aromatics Based on Oligothiophene-Functionalized Truxene: Synthesis, Properties, and Facile Emissive Wavelength Tuning. J. Am. Chem. Soc. 2003, 125, 9944-9945.

4. Pei, J.;* Ni, J.; Zhou, X.-H.; Cao, X.-Y.; Lai, Y.-H. Regioregular Head-to-Tail Oligothiophene-Functionalized 9, 9'-Spirobifluorene Derivatives. 2. NMR Characterization, Thermal Behavior, and Electrochemical Properties. J. Org. Chem. 2002, 67, 8104-8113.

3. Chen, J.; Zhang, Y.; Cao, X.-Y.; Wang, J.; Chen, Y.; Zhao, Y.-F.* Monitoring the Hydrolysis of p-Nitrophenyl Acetate Catalyzed by Seryl-Histidine with Electrospray Ionization Mass Spectrometry. Chin. J. Chem. 2002, 20, 1097-1101.

2. Pei, J.;* Ni, J.; Zhou, X.-H.; Cao, X.-Y.; Lai, Y.-H. Head-to-Tail Regioregular Oligothiophene-Functionalized 9,9'-Spirobifluorene Derivatives. 1. Synthesis. J. Org. Chem. 2002, 67, 4924-4936.

1. Zhao, C.; Li, P.; Cao, X.; Xi, Z.* Lewis Acid Mediated Reactions of Zirconacyclopentadienes with Aldehydes. One-pot Synthesis Route to Indene and Cyclopentadiene Derivatives from Aldehydes and Benzyne or Alkynes. Chem. Eur. J. 2002, 8, 4292-4298.