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A Missing Member of Conjugated N-Heterocycles: Realizing Pyrido[1,2-ɑ]azepine by Reacting Ruthenium Alkenylcarbene Complex with Alkyne (2018-03-21)

Date:2018-03-21 16:49    Author:jiang   
Despite the excellent chemical properties of N-heterocycles, pyrido[1,2-α]azepine remains elusive due to its potential antiaromaticity and lability. Herein, we demonstrate the synthesis and characterization of the first bicyclic pyrido[1,2-α]azepine that leverages the coordination to the ruthenium center to promote the stability of N-bridged bicycle.
 


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