Publications

2019
 

106. Zhuo, Q.;† Zhang, H.;† Ding, L.; Lin, J.; Zhou, X.; Hua, Y.; Zhu, J.; Xia, H.Rhodapentalenes: Pincer Complexes with Internal Aromaticity. iScience 2019, 191214-1224.[Link](Zhuo and Zhang contributed equally to this work.)

105. Luo, M.; Deng, Z.; Ruan, Y.; Cai, Y.; Zhuo, K.; Zhang, H.;Xia, H. Reactions of Metallacyclopentadiene with Terminal Alkynes: Isolation and Characterization of Metallafulvenallene Complexes. Organometallics 201938, 3053-3059.[Link](ACS Editors’ Choice)

104. Huang, X.;† Tang, C.;† Li, J.;† Chen, L.-C.;† Zheng, J.; Zhang, P.; Le, J.; Li, R.; Li, X.; Liu, J.;Yang, Y.; Shi, J.; Chen, Z.; Bai, M.; Zhang, H. L.; Xia, H.; Cheng, J.;Tian, Z. Q.; Hong, W.Electric Field-induced Selective Catalysis of Single-Molecule Reaction. Sci. Adv. 2019, 5, eaaw3072.[Link](Huang, Tang, Li and Chen contributed equally to this work.)

103. Tang, C.; Chen, L.; Zhang, L.; Chen, Z.; Li, G.; Yan, Z.; Lin, L.; Liu, J.; Huang, L.; Ye, Y.; Hua, Y.; Shi, J.; Xia, H.;Hong, W.Multicenter-Bond-Based Quantum Interference in Charge Transport Through Single-Molecule Carborane Junctions. Angew. Chem., Int. Ed. 201958, 10601-10605.[Link]

102. Chen, Z.;† Chen, L.;† Liu, J.; Li, R.; Tang, C.; Hua, Y.; Chen, L.; Shi, J.; Yang, Y.; Liu, J.; Zheng, J.; Chen, L.; Cao, J.; Chen, H.; Xia, H.;Hong, W.Modularized Tuning of Charge Transport through Highly Twisted and Localized Single-Molecule Junctions. J. Phys. Chem. Lett. 2019, 10, 3453-3458.[Link](Chen, Z.; and Chen, L. contributed equally to this work.)

101. Wu, F.; Huang, W.; Zhuo, K.; Hua, Y.; Lin, J.; He, G.;Chen, J.; Nie, L.;Xia, H.Carbolong Complexes as Photothermal Materials. Chin. J. Org. Chem. 2019, 39, 1743-1752.[Link]

100. Deng, Z.; Zhu, C.; Hua, Y.; He, G.; Guo, Y.; Lu, R.; Cao, X.; Chen, J.;Xia, H.Synthesis and Characterization of Metallapentalenoxazetes from the [2+2] Cycloaddition of Metallapentalynes with Nitrosoarenes. Chem. Commun. 201955, 6237-6240.[Link]

99. Lin, J.; Ding, L.; Zhuo, Q.; Zhang, H.;Xia, H.Formal [2+2+2] Cycloaddition Reaction of a Metal–Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex. Organometallics 201925, 5077-5085.[Link]

98. Zhou, X.; Pang, X.; Nie, L.; Zhu, C.; Zhuo, K.; Zhuo, Q.; Chen, Z.; Liu, G.; Zhang, H.;* Lin, Z.; Xia, H. Successive Modification of Polydentate Complexes Gives Access to Planar Carbon- and Nitrogen-based Ligands. Nat. Commun. 2019, 10, 1488.[Link]
This article has been highlighted by: ChemistryViews[SourceNature Communications Editors’ Highlights[Source]

97. Li, J.; Lin, Y. M.;Zhang, H.; Chen, Y.; Lin, Z.; Xia, H.Access to Metal-Bridged Osmathiazine Derivatives by a Formal [4+2] Cyclization. Chem. - Eur. J. 201925, 5077-5085.[Link]

96. Zhang, H.;† Zhao, H.;† Zhuo, K.; Hua, Y.; Chen, J.; He, X.;* Weng, W.;* Xia, H.* "Carbolong" Polymers with Near Infrared Triggered, Spatially Resolved and Rapid Self-Healing Properties. Polym. Chem. 201910, 386-394.[Link](†Zhang and Zhao contributed equally to this work.)

 

2018
 

95. Li, J.; Kang, H.; Zhuo, K.; Zhuo, Q.; Zhang, H.; Lin, Y.-M.;Xia, H.Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative. Chin. J. Chem. 2018, 36, 1156-1160.[Link]

94. Chen, Z.;† Wang, T.;† Sun, T.; Chen, Z.; Sheng, T.; Hong, Y.-H.; Nan, Z.-A.; Zhu, J.; Zhou, Z.-Y.;Xia, H.;Sun, S.-G. Nickel Complexes with Non-innocent Ligands as Highly Active Electrocatalysts for Hydrogen Evolution. Chin. J. Chem. 2018, 36, 1161-1164.[Link](†Chen and Wang contributed equally to this work.)

93. Lu, Z.;† Lin, Q.;† Cai, Y.; Chen, S.; Chen, J.;* Wu, W.; He, X.;* Xia, H.* Cylindrical Nir-Responsive Metallopolymer Containing Möbius Metalla-Aromatics. ACS Macro Lett. 2018, 7, 1034-1038.[Link](†Lu and Lin contributed equally to this work.)

92. Hua, Y.; Lan, Q.; Fei, J.; Tang, C.; Lin, J.; Zha, H.; Chen, S.; Lu, Y.; Chen, J.;He, X.;* Xia, H. Metallapentalenofuran: Shifting Metallafuran Rings Promoted by Substituent Effects. Chem. - Eur. J. 2018, 24, 14531-14538.[Link]

91. Zhuo, Q.;† Zhang, H.;† Hua, Y.; Kang, H.; Zhou, X.; Lin, X.; Chen, Z.; Lin, J.; Zhuo, K.; Xia, H.* Constraint of a Ruthenium-Carbon Triple Bond to a Five-Membered Ring. Sci. Adv. 2018, 4 (6), eaat0336.[Link](†Zhuo and Zhang contributed equally to this work.)

 

90. Zhu, C.; Xia, H.* Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metals. Acc. Chem. Res201851, 1691-1700.[Link]

89. Zhou, X.; Li, Y.; Shao, Y.; Hua, Y.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes. Organometallics 2018, 37, 1788-1794.[Link]

88. Lin, Q.;† Li, S.;† Lin, J.;† Chen, M.; Lu, Z.; Tang, C.; Chen, Z.; He, X.; Chen, J.;* Xia, H.* Synthesis and Characterization of Photothermal Osmium Carbolong Complexes. Chem. - Eur. J. 2018, 24, 8375-8381.[Link](Lin, Q., Li, S. and Lin, J. contributed equally to this work.)

87. Zhou, X.; Huang, F.; Tang, C.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Xia, H. A Missing Member of Conjugated N-Heterocycles: Realizing Pyrido[1,2-α]azepine by Reacting Ruthenium Alkenylcarbene Complex with Alkyne. Chem. Commun. 201854, 4009-4012.[Link]

86. Wang, T.;† Chen, Z.-X.;† Chen, Y.-G.; Yang, L.-J.;Yang, X.-D.; Ye, J.-Y.; Xia, H.-P.; Zhou, Z.-Y.;* Sun, S.-G. Identifying the Active Site of N-Doped Graphene for Oxygen Reduction by Selective Chemical Modification. ACS Energy Lett. 20183, 986-991.[Link](Wang and Chen contributed equally to this work.)

85. Wang, T.;† Chen, Z.-X.;† Yu, S.; Sheng, T.; Ma, H.-B.; Chen, L.-N.; Rauf, M.; Xia, H.-P.; Zhou, Z.-Y.;* Sun, S.-G. Constructing Canopy-Shaped Molecular Architectures to Create Local Pt Surface Sites with High Tolerance to H2S and CO for Hydrogen Electrooxidation. Energy Environ. Sci. 201811, 166-171.[Link](Wang and Chen contributed equally to this work.)

84. Lu, Z.; Cai, Y.; Wei, Y; Lin, Q.; Chen, J.;* He, X.; Li, S.; Wu, W.; Xia, H.* Photothermal Möbius Aromatic Metallapentalenofuran and Its NIR-Responsive Copolymer. Polym. Chem. 20189, 2092-2100. (Cover Paper) [Link]
Cover Profile [PDF]
Cover Picture [PDF]

83. Chen, J.;* Lin, Q.; Li, S.; Lu, Z; Lin, J.; Chen, Z.; Xia, H.* Synthesis and Characterization of an Osmapentalene Derivative Containing a β-Agostic Os···H–C(sp3) Interaction. Organometallics 201837, 618-623.[Link]

82. Zhu, C.; Zhu, J.; Zhou, X.; Zhu, Q.; Yang, Y.; Wen, T. B.; Xia, H.* Isolation of an Eleven‐Atom Polydentate Carbon‐Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne. Angew. Chem., Int. Ed. 201857, 3154-3157. (VIP Paper) [Link]

clip_image006.jpg

81. Zhou, X.; Zhang, H.* Reactions of Metal-Carbon Bonds within Six-Membered Metallaaromatic Rings. Chem. - Eur. J. 201824, 8962-8973.[Link]

80. Hua, Y.; Zhang, H.;* Xia, H.* Aromaticity: History and Development. Chin. J. Org. Chem. 201838, 11-28.[Link]

79. Wang, H.;† Zhou, X.;† Xia, H.* Metallaaromatics Containing Main‐Group Heteroatoms. Chin. J. Chem. 201836, 93-105.[Link](†Wang and Zhou contributed equally to this work.)

78. Zhou, X.; Wu, J.; Hao, Y.; Zhu, C.; Zhuo, Q.; Xia, H.;* Zhu, J.* Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity. Chem. - Eur. J. 201824, 2389-2395. (Cover Paper) [Link]
Cover Profile [
Link]
Cover Picture [
Link]

clip_image008.jpg

77. Yang, C.;† Lin, G.;† Zhu, C.; Pang, X.; Zhang, Y.; Wang, X.; Li, X.; Wang, B.;* Xia, H.;* Liu, G.* Metalla-Aromatic Loaded Magnetic Nanoparticles for MRI/Photoacoustic Imaging-Guided Cancer Phototherapy. J. Mater. Chem. B 20186, 2528-2535. (Frontispiece Paper) [Link](Yang, Lin and Zhu contributed equally to this work.)

clip_image010.jpg

2017
 

76. Huang, J.; Zhou, X.; Zhao, Q.; Li, S.; Xia, H.* Synthesis, Characterization and Electrochemical Properties of 4,5-Diazafluoren-9-yl or Fluoren-9-yl Terminated Homobimetallic Ruthenium and Osmium Allenylidene, Alkynyl-Allenylidene Complexes. Chin. J. Chem. 2017, 35, 420-428.[Link]

75. Zhuo, Q.; Lin, J.; Hua, Y.; Zhou, X.; Shao, Y.; Chen, S.; Chen, Z.; Zhu, J.; Zhang, H.; Xia, H.* Multiyne Chains Chelating Osmium via Three Metalcarbon σ Bonds. Nat. Commun. 2017, 8, 1912.[Link
This article has been highlighted by: Xiamen University[
SourceCollege of Chemistry and Chemical Engineering, Xiamen University[Source] X-MOL[Source].

clip_image012.jpg

74. Huang, Z.-A.; Lan, Q.; Hua, Y.; Chen, Z.; Zhang, H.;* Lin, Z.; Xia, H. Color-Tuning Strategy for Iridapolycycles [(N∧N)Ir(CC)ClPPh3]by the Synergistic Modifications on Both the CC and NN Units. Organometallics 201736, 4802–4809.[Link]

73. Long, L.; Zhou, X.; Wang, T.; Chen, Z.; Zhang, H.;* Xia, H.* Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine. Organometallics 2017, 36, 4184−4190.[Link]

72. Li, R.;† Lu, Z.; Cai, Y.; Jiang, F.; Tang, C.; Chen, Z.; Zheng, J.; Pi, J.; Zhang, R.; Liu, J.; Chen, Z.; Yang, Y.; Shi, J.; Hong, W.;* Xia, H.* Switching of Charge Transport Pathways via Delocalization Changes in Single-Molecule Metallacycles Junctions. J. Am. Chem. Soc. 2017139, 14344-14347. (Inside Cover Paper) [Link](Li and Lu contributed equally to this work.)

clip_image014.jpg

71. He, X.;* He, X.; Li, S.; Zhuo, K.; Qin, W.; Dong, S.; Chen, J.; Ren, L.; Liu, G.; Xia, H.* Amphipathic Metal-containing Macromolecules with Photothermal Properties. Polym. Chem. 20178, 3674-3678. (Inside Cover Paper)[Link]

clip_image016.jpg

70. Zhu, C.; Wu, J.; Li, S.; Yang, Y.; Zhu, J.; Lu, X.; Xia, H.* Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-Membered Rings. Angew. Chem., Int. Ed. 201756, 9067-9071.[Link]

clip_image018.jpg

69. Lu, Z.; Chen, J.; Xia, H.* Synthesis of Olefinic Carbolong Complexes. Chin. J. Org. Chem. 201737, 1181-1188.[Link]

68. Lu, Z.;† Zhu, C.; Cai, Y.; Zhu, J.; Hua, Y.; Chen, Z.; Chen, J.;* Xia, H.* Metallapentalenofurans and Lactone-Fused Metallapentalynes. Chem. - Eur. J. 201723, 6426-6431.[Link](Lu and Zhu contributed equally to this work.)

67. Luo, M.; Long, L.; Zhang, H.;* Yang, Y.; Hua, Y.; Liu, G.; Lin, Z.;* Xia, H.* Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates. J. Am. Chem. Soc. 2017,139, 1822-1825.[Link]

clip_image020.jpg

66. Zhu, Q.; Zhu, C.; Deng, Z.; He, G.;* Chen, J.; Zhu, J.; Xia, H.* Synthesis and Characterization of Osmium Polycyclic Aromatic Complexes via Nucleophilic Reactions of Osmapentalyne. Chin. J. Chem. 201735, 628-634.[Link]
 

2016
 

65. Zhu, C.;† Yang, C.; Wang, Y.; Lin, G.; Yang, Y.; Wang, X.; Zhu, J.; Chen, X.; Lu, X.;* Liu, G.;* Xia, H.* CCCCC Pentadentate Chelates with Planar Möbius Aromaticity and Unique Properties. Sci. Adv. 20162, e1601031.[Link](Zhu and Yang contributed equally to this work.)
This article has been highlighted by: C & EN[Source] PhysOrg[SourceNSFC[Source]

clip_image022.jpg

64. Chen, J.;† Huang, Z.-A.; Lu, Z.; Zhang, H.;* Xia, H.* Synthesis of Cyclic Vinylidene Complexes and Azavinylidene Complexes by Formal [4+2] Cyclization Reactions. Chem. - Eur. J. 2016, 22, 5363-5375.[Link](Chen and Huang contributed equally to this work.)

63. Zhuo, Q.; Zhou, X.; Kang, H.; Chen, Z.; Yang, Y.; Han, F.; Zhang, H.;* Xia, H.* Synthesis of Fused Metallaaromatics via Intramolecular C−H Activation of Thiophenes. Organometallics 2016, 35, 1497-1504.[Link]

62. Zhuo, Q.;† Chen, Z.; Yang, Y.; Zhou, X.; Han, F.; Zhu, J.; Zhang, H.;* Xia, H.* Synthesis of Aromatic Ruthenabenzothiophenes via C–H Activation of Thiophenes. Dalton Trans. 201645, 913-917.[Link](Zhuo and Chen contributed equally to this work.)

61. Luo, M.; Zhu, C.; Chen, L.; Zhang, H.;* Xia, H.* Halogenation of Carbyne Complexes: Isolation of Unsaturated Metallaiodirenium Ion and Metallabromirenium Ion. Chem. Sci. 20167, 1815-1818.[Link]

clip_image024.jpg

2015
 

60. Xu, H.;† Huang, Z.-A.; Guo, X.; Yang, Y.; Hua, Y.; Cao, Z.; Li, S.;* Xia, H.* Sequential Construction Strategy for Rational Design of Luminescent Iridacycles. Organometallics 201534, 4229-4237.[Link](Xu and Huang contributed equally to this work.)

59. Zhou, X.; He, X.; Lin, J.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Wang, J.; Xia, H.* Reactions of Osmium Hydrido Alkenylcarbyne with Allenoates: Insertion and [3 + 2] Annulation. Organometallics 201534, 1742-1750.[Link]

58. Zhu, C.; Yang, Y.; Wu, J.; Luo, M.; Fan, J.; Zhu, J.;* Xia, H.* Five-Membered Cyclic Metal Carbyne: Synthesis of Osmapentalynes by the Reactions of Osmapentalene with Allene, Alkyne, and Alkene. Angew. Chem., Int. Ed. 201554, 7189-7192.[Link]

clip_image026.jpg

57. Wang, T.; Han, F.; Huang, H.; Li, J.; Zhang, H.;* Zhu, J.; Lin, Z.;* Xia, H.* Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation. Sci. Rep. 20155, 9584.[Link]

56. Wei, Y.; Zhou, X.; Hong, G.; Chen, Z.; Zhang, H.;* Xia, H.* Reactions of Osmapyridinium with Terminal Alkynes. Org. Chem. Front. 2015, 2, 560-568.[Link]

55. Zhu, C.; Yang, Y.; Luo, M.; Yang, C.; Wu, J.; Chen, L.; Liu, G.; Wen, T.; Zhu, J.;* Xia, H.* Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics. Angew. Chem., Int. Ed. 201554, 6181-6185.[Link]
Cover Picture[PDF]

clip_image028.jpg

54. Xu, H.; Xu, Y.; Pang, X.; He, Y.; Jung, J.; Xia, H.;* Lin, Z.* A General Route to Nanocrystal Kebabs Periodically Assembled on Stretched Flexible Polymer Shish. Sci. Adv. 20151, e1500025.[Link]
This article has been highlighted by: Scienceshot[SourceSciences[SourceGeorgia Institute of Technology[SourcePhysOrg[SourceScienceDaily[Source]Nanowerk[SourceWorld of Chemicals[SourceNanotechnology Now[Source]Pinterest[SourceFnews[SourceNano Daily[SourceTrendsSoul[Sourcemore[Source]

clip_image030.jpg

53. Xu, H.; Pang, X.; He, Y.; He, M.; Jung, J.; Xia, H.;Lin, Z.* An Unconventional Route to Monodisperse and Intimately Contacted Semiconducting Organic–Inorganic Nanocomposites. Angew. Chem., Int. Ed. 201554, 4636-4640.(Inside Cover)[Link]
Cover Picture[PDF]

clip_image032.jpg

52. Zhu, C.; Zhou, X.; Xing, H.; An, K.; Zhu, J.;* Xia, H.* σ-Aromaticity in an Unsaturated Ring: Osmapentalene Derivatives Containing a Metallacyclopropene Unit. Angew. Chem., Int. Ed. 201554, 3102-3106.[Link]

clip_image034.jpg

51. Han, F.; Li, J.; Zhang, H.;* Wang, T.; Lin, Z.;* Xia, H.* Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene. Chem. - Eur. J. 201521, 565-567.[Link]

50. Chen, J.;† Huang, Z.-A.; Hua, Y.; Zhang, H.;* Xia, H. Synthesis of Five-Membered Osmacycles with Osmium–Vinyl Bonds from Hydrido Alkenylcarbyne Complexes. Organometallics 201534, 340-347.[Link](Chen and Huang contributed equally to this work.)

49. Lin, Z.;* Zhu, C.; Xia, H. HRMS Studies on the Fragmentation Pathways of Metallapentalyne. Spectrochim. Acta, Part A 2015136, 906-910.[Link]
 

2014
 

48. Wang, X.; Zhu, C.; Xia, H.;* Zhu, J.* Theoretical Study on the Stability and Aromaticity of Metallasilapentalynes. Organometallics 201433, 1845-1850.[Link]

47. Han, F.; Wang, T.; Li, J.; Zhang, H.; Zhang, L.; He, X.;* Xia, H.* Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex. Organometallics 201433, 5301-5307.[Link]

46. Zhang, H.;* Lin, R.; Li, J.; Zhu, J.; Xia, H. Interconversion between Ruthenacyclohexadiene and Ruthenabenzene: A Combined Experimental and Theoretical Study. Organometallics 201433, 5606-5609.[Link]

45. Zhou, X.; Zhang, C.; Lin, Y.; He, X.; Zhang, Y.; Wang, J.; Xia, H.* 1,2-Migration in the Reactions of Ruthenium Vinylcarbene with Propargyl Alcohols. Org. Chem. Front. 20141, 1077-1082.[Link]

44. Zhuo, Q.; Wang, T.; Zhou, X.; Zhang, H.* Progresses of Ring Expansion Reaction of Small Transitional Metallacyclic Compounds. Chin. J. Org. Chem. 201434, 1471-1486.[Link]

43. Han, F.; Wang, T.; Li, J.; Zhang, H.;Xia, H.* m-Metallaphenol: Synthesis and Reactivity Studies. Chem. - Eur. J. 201420, 4363-4372.(Cover Paper)[Link]
Cover Picture[PDF
Cover Profile[PDF]

clip_image036.jpg

42. Zhu, C.; Zhu, Q.; Fan, J.; Zhu, J.; He, X.; Cao, X.-Y.;* Xia, H.* A Metal-Bridged Tricyclic Aromatic System: Synthesis of Osmium Polycyclic Aromatic Complexes. Angew. Chem., Int. Ed. 2014,53, 6232-6236.[Link]

clip_image038.jpg

41. Zhu, C.; Luo, M.; Zhu, Q.; Zhu, J.;* Schleyer, P. v. R.; Wu, J. I.-C.; Lu, X.; Xia, H.* Planar Möbius Aromatic Pentalenes Incorporating 16 and 18 Valence Electron Osmiums. Nat. Commun. 20145, 3265.[Link]

clip_image040.jpg

40. Cao, X.-Y.; Zhao, Q.; Lin, Z.;* Xia, H.* The Chemistry of Aromatic Osmacycles. Acc. Chem. Res. 201447, 341-354.[Link]

clip_image042.jpg

2013

 

39. Zhang, C.; Zhang, H.; Wei, A.; He, X.;* Xia, H.* Synthesis of Ruthena-polycyclic Complexes by Ruthenium-Vinylcarbene Complex. Acta Chim. Sinica 2013, 71, 1373-1378.[Link]

38. Xie, H.; Zhang, H.; Lin, Z.* DFT Studies on the Palladium-Catalyzed Dearomatization Reaction between Chloromethylnaphthalene and the Cyclic Amine Morpholine. Organometallics 2013, 32, 2336-2343.[Link]

37. Xie, H.; Zhang, H.; Lin, Z.* DFT Studies on the Mechanisms of Palladium-Catalyzed Intramolecular Arylation of a Silyl C(sp3)–H Bond. New J. Chem. 2013, 37, 2856-2861.[Link]

36. Wang, T.; Zhu, J.; Han, F.; Zhou, C.; Chen, H.; Zhang, H.;* Xia, H.* Synthesis of Five‐Membered Osmacycloallenes and Conversion into Six‐Membered Osmacycloallenes. Angew. Chem., Int. Ed. 201352, 13361-13364.[Link]

clip_image044.jpg

35. Wang, T.;† Zhang, H.;† Han, F.; Long, L.; Lin, Z.;* Xia, H.* Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization. Angew. Chem., Int. Ed. 201352, 9251-9255.[Link](†Wang and Zhang contributed equally to this work.)

clip_image046.jpg

34. Zhu, C.; Li, S.; Luo, M.; Zhou, X.; Niu, Y.; Lin, M.; Zhu, J.;* Cao, Z.; Lu, X.; Wen, T.; Xie, Z.; Schleyer, P. v. R.; Xia, H.* Stabilization of Anti-aromatic and Strained Five-Membered Rings with a Transition Metal. Nat. Chem. 20135, 698–703.[Link]
This article has been highlighted by: 
ACS "Noteworthy Chemistry"
[Source
Nature Chemistry[Source
Nature China[Source]

clip_image048.jpg

33. Chen, J.; Zhang, C.; Xie, T.; Wen, T. B.; Zhang, H.;* Xia, H.* Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes. Organometallics 201332, 3993-4001.[Link]

32. Zhang, C.; Zhang, H.; Zhang, L.; Wen, T. B.; He, X.;* Xia, H.* Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization. Organometallics 201332, 3738-3743.[Link]

31. Wang, T.;† Zhang, H.;† Han, F.; Long, L.; Lin, Z.;* Xia, H.* cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study. Chem. - Eur. J. 201319, 10982-10991.[Link](†Wang and Zhang contributed equally to this work.)

30. Niu, Y.; Han, F.; Zhang, Q.; Xie, T.; Lu, L.; Li, S.;* Xia, H.* Off/On Fluorescent Chemosensors for Organotin Halides Based on Binuclear Ruthenium Complexes. Angew. Chem., Int. Ed. 201352, 5599-5603.[Link]

clip_image050.jpg

29. Zhu, C.; Cao, X.;* Xia, H.* Double Stabilization of Highly Strained Six-Membered Rings by Phosphonium and Transition Metal. Chin. J. Org. Chem. 201333, 657-662.Invited and Cover Paper)[Link]

28. Zhao, Q.; Cao, X.-Y.;* Wen, T. B.; Xia, H.* From Osmium Hydrido Vinylidene to Osmacycles: The Key Role of Osmabutadiene Intermediates. Chem. - Asian J. 20138, 269-275.[Link]
 

2012
 

27. Wang, T.;† Zhang, H.;† Han, F.; Lin, R.; Lin, Z.;* Xia, H.* Synthesis and Characterization of a Metallapyridyne Complex. Angew. Chem., Int. Ed. 201251, 9838-9841.[Link](†Wang and Zhang contributed equally to this work.)

clip_image052.jpg

26. Zhao, Q.; Zhu, J.; Huang, Z.-A.; Cao, X.-Y.;* Xia, H.* Conversions of Osmabenzyne and Isoosmabenzene. Chem. - Eur. J. 201218, 11597-11603. (Inside Cover Paper)[Link]

25. Lin, R.; Zhao, J.; Chen, H.; Zhang, H.;* Xia, H.* Interconversion of Metallabenzenes and Cyclic η2-Allene-Coordinated Complexes. Chem. - Asian J. 20127, 1915-1924.[Link]
 

2011
 

24. Zhao, Q.; Gong, L.; Xu, C.; Zhu, J.;* He, X.; Xia, H.* Stable Iso-osmabenzenes from a Formal [3+3] Cycloaddition Reaction of Metal Vinylidene with Alkynols. Angew. Chem., Int. Ed. 201150, 1354–1358.[Link]

clip_image054.jpg

23. Lin, R.; Zhang, H.;* Li, S.; Wang, J.; Xia, H.* New Highly Stable Metallabenzenes via Nucleophilic Aromatic Substitution Reaction. Chem. - Eur. J. 201117, 4223–4231. (Inside Cover Paper)[Link]

22. Lin, R.; Zhang, H.; Li, S.;* Chen, L.; Zhang, W.; Wen, T. B.; Zhang, H.; Xia, H.* pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene with L- and D-Cysteine. Chem. - Eur. J. 201117, 2420–2427.[Link]
This article has been highlighted by ACS "Noteworthy Chemistry". [Source]

 

Pre 2010
 

21. Zhang, H.;* Lin, R.; Hong, G.; Wang, T.; Wen, T. B.; Xia, H.* Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes. Chem. - Eur. J. 201016, 6999–7007.[Link]

20. He, X.; Gong, L.; Kräling, K.; Gründler, K.; Frias, C.; Webster, R. D.; Meggers, E.;* Prokop, A.;* Xia, H.* Unusual η2-Allene Osmacycle with Apoptotic Properties, ChemBioChem 201011, 1607-1613.[Link]

19. Zhang, H.;* Lin, R.; Luo, M.; Xia, H.* Synthesis and Characterization of Stable Osmafuran Starting from HC≡CCH(OH)C≡CH and OsHCl(CO)(PPh3)3. Sci. China: Chem. 201053, 1978–1981.[Link]

18. He, X.-M.;* Liu, Q.; Gong, L.; Lin, Y.; Wen, T. B.* Synthesis of an Osmafuran from Photochemical Hydrolysis of OsCl2(CH=C(PPh3)C(O)-η2-CH=CH2)(PPh3)2. Inorg. Chem. Commun. 201013, 342–345.[Link]

17. Huang, J.; Lin, R.; Wu, L.; Zhao, Q.; Zhu, C.; Wen, T. B.;* Xia, H.* Synthesis, Characterization, and Electrochemical Properties of Bisosmabenzenes Bridged by Diisocyanides. Organometallics 201029, 2916–2925.[Link]

16. Lin, Y.; Xu, H.; Gong, L.; Wen, T. B.; He, X.-M.;* Xia, H.* C-H Bond Activation and Subsequent C(sp(2))-C(sp(3)) Bond Formation: Coupling of Bromomethyl and Triphenylphosphine in an Iridium Complex. Organometallics 201029, 2904–2910.[Link]

15. Liu, B.; Wang, H.; Xie, H.; Zeng, B.; Chen, J.; Tao, J.; Wen, T. B.; Cao, Z.; Xia, H.* Osmapyridine and Osmapyridinium from a Formal [4+2] Cycloaddition Reaction. Angew. Chem., Int. Ed. 200948, 5430–5434. (VIP and Frontispiece Paper )[Link]
This article has been highlighted by RSC "Chemistry Word". [Source]

14. Wang, T.; Li, S.; Zhang, H.; Lin, R.; Han, F.; Lin, Y.; Wen, T. B.; Xia, H.* Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole. Angew. Chem. Int. Ed. 200948, 6453–6456.[Link]

13. Liu, B.; Xie, H.; Wang, H.; Wu, L.; Zhao, Q.; Chen, J.; Wen, T. B.; Cao, Z.;* Xia, H.* Selective Synthesis of Osmanaphthalene and Osmanaphthalyne by Intramolecular C-H Activation. Angew. Chem., Int. Ed. 200948, 5461–5464.[Link]

12. Gong, L.; Chen, Z.; Lin, Y.; He, X.;* Wen, T. B.; Xu, X.; Xia, H.* Osmabenzenes from Osmacycles Containing an η2-Coordinated Olefin. Chem. - Eur. J. 200915, 6258–6266.[Link]

11. Zhang, H.; Wu, L.; Lin, R.; Zhao, Q.; He, G.; Yang, F.; Wen, T. B.; Xia, H.* Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3 Substituents. Chem. - Eur. J. 200915, 3546–3559.[Link]

10. Lin, Y.; Gong, L.; Xu, H.; He, X.; Wen, T. B.; Xia, H.* Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran. Organometallics 200928, 1524–1533.[Link]

9. Gong, L.; Lin, Y.; Wen, T. B.;* Xia, H.* Synthesis of Coordinated η2-α,β-Unsaturated Ketone Osmacycles from an Osmium-Coordinated Alkyne Alcohol Complex. Organometallics 200928, 1101–1111.[Link]

8. Wu, L.; Feng, L.; Zhang, H.; Liu, Q.; He, X.; Yang, F.; Xia, H.* Synthesis and Characterization of a Novel Dialdehyde and Cyclic Anhydride. J. Org. Chem. 200873, 2883–2885.[Link]

7. Gong, L.; Lin, Y.; Wen, T. B.; Zhang, H.; Zeng, B.; Xia, H.* Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction. Organometallics 200827, 2584–2589.[Link]

6. Gong, L.; Lin, Y.; He, G.; Zhang, H.; Wang, H.; Wen, T. B.;* Xia, H.* Synthesis and Characterization of an Air-Stable p-Osmaphenol. Organometallics 200827, 309–311.[Link]

5. Gong, L.; Wu, L.; Lin, Y.; Zhang, H.; Yang, F.; Wen, T.; Xia, H.* Synthesis and Characterization of a Bimetallic Iridium Complex with a Ten sp2-Carbon Chain Bridge. Dalton Trans. 2007, 4122–4125. (Hot Article)[Link]

4. Zhang, H.; Feng, L.; Gong, L.; Wu, L.; He, G.; Wen, T.; Yang, F.; Xia, H.* Synthesis and Characterization of Stable Ruthenabenzenes Starting From HCCCH(OH)CCH. Organometallics 200726, 2705–2713.[Link]

3. Zhang, H.; Xia, H.;* He, G.; Wen, T. B.; Gong, L.; Jia, G.Synthesis and Characterization of Stable Ruthenabenzenes. Angew. Chem., Int. Ed. 200645, 2920–2923. (VIP)[Link]
This article has been highlighted by ACS "Heart Cut".

2. Xia, H.;* He, G.; Zhang, H.; Wen, T. B.; Sung, H. H. Y.; Williams, I. D.; Jia, G.* Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3 (X = Cl, Br). J. Am. Chem. Soc. 2004126, 6862–6863.[Link]
    This article has been highlighted by ACS "Chemical & Engineering News". [Source]

clip_image064.jpg

1. He, G.; Xia, H.;* Jia, G. Progress in the Synthesis and Reactivity Studies of Metallabenzenes. Chin. Sci. Bull. 200449, 1543–1553.[Link]