Professors
Zhang Hong
Date:2018-06-20 19:08    Author:jiang   

Education

09/2001–08/2007  Doctorate Student, Organic Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, China, Supervisor: Prof. Haiping Xia
09/1997-07/2001 Undergraduate Student, Material Science, College of Chemistry and Chemical Engineering, Xiamen University, China, Supervisor: Prof. Haiping Xia


Research Experience


09/2007–08/2011

Assistant Professor, Organic Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, China

04/2012–04/2013

Postdoctoral Fellow, Computational Chemistry, Department of Chemistry, The Hong Kong University of Science& Technology, Hong Kong, Supervisor: Prof. Zhenyang Lin 

08/2011–08/2018

Associate Professor, Organic Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, China

08/2018– present

Professor, Organic Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, China

Contact me:

Lu Jiaxi Building 742, College of Chemistry and Chemical Engineering, Xiamen University
Tel:0592-2184520
Email:zh@xmu.edu.cn

Awards and Honors:

Thieme Chemistry Journals Award (2019)
Program for New Century Excellent Talents in Fujian Province University (2018)

Publication:

52. Zhou, X.; Pang, X.; Nie, L.; Zhu, C.; Zhuo, K.; Zhuo, Q.; Chen, Z.; Liu, G.; Zhang, H.;* Lin, Z.; Xia, H. Successive Modification of Polydentate Complexes Gives Access to Planar Carbon- and Nitrogen-based Ligands. Nat. Commun. 201910, 1488.

51. Li, J.; Lin, Y. M.;Zhang, H.; Chen, Y.; Lin, Z.; Xia, H.* Access to Metal-Bridged Osmathiazine Derivatives by a Formal [4+2] Cyclization. Chem. - Eur. J. 2019, 25, 5077-5085.

50. Li, J.; Kang, H.; Zhuo, K.; Zhuo, Q.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative. Chin. J. Chem. 201836, 1156-1160.

49. Zhuo, Q.;† Zhang, H.;† Hua, Y.; Kang, H.; Zhou, X.; Lin, X.; Chen, Z.; Lin, J.; Zhuo, K.; Xia, H.* Constraint of a Ruthenium-Carbon Triple Bond to a Five-Membered Ring. Sci. Adv. 2018, 4 (6), eaat0336.(†Zhuo and Zhang contributed equally to this work.)

48. Zhou, X.; Li, Y.; Shao, Y.; Hua, Y.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes. Organometallics 2018, 37, 1788-1794.

47. Zhou, X.; Huang, F.; Tang, C.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Xia, H. A Missing Member of Conjugated N-Heterocycles: Realizing Pyrido[1,2-Α]azepine by Reacting Ruthenium Alkenylcarbene Complex with Alkyne. Chem. Commun. 2018, 54, 4009-4012.

46. Zhou, X.; Zhang, H.* Reactions of Metal-Carbon Bonds within Six-Membered Metallaaromatic Rings. Chem. - Eur. J. 201824, 8962-8973.

45.  Hua, Y.; Zhang, H.;* Xia, H.* Aromaticity: History and Development. Chin. J. Org. Chem. 201838, 11-28.

44. Zhuo, Q.; Lin, J.; Hua, Y.; Zhou, X.; Shao, Y.; Chen, S.; Chen, Z.; Zhu, J.; Zhang, H.; Xia, H.* Multiyne Chains Chelating Osmium via Three Metalcarbon σ Bonds. Nat. Commun. 20178, 1912.

43. Long, L.; Zhou, X.; Wang, T.; Chen, Z.; Zhang, H.;* Xia, H.* Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine. Organometallics 201736, 4184−4190.

42. Huang, Z.-A.; Lan, Q.; Hua, Y.; Chen, Z.; Zhang, H.;* Lin, Z.; Xia, H. Color-Tuning Strategy for Iridapolycycles [(N∧N)Ir(C∧C)ClPPh3]by the Synergistic Modifications on Both the C∧C and N∧N Units. Organometallics 201736, 4802–4809.

41. Luo, M.; Long, L.; Zhang, H.;* Yang, Y.; Hua, Y.; Liu, G.; Lin, Z.;* Xia, H.* Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates. J. Am. Chem. Soc2017,139, 1822-1825.

40. Chen, J.;† Huang, Z.-A.;† Lu, Z.; Zhang, H.;* Xia, H.* Synthesis of Cyclic Vinylidene Complexes and Azavinylidene Complexes by Formal [4+2] Cyclization Reactions. Chem. - Eur. J. 2016, 22, 5363-5375.(Chen and Huang contributed equally to this work.)

39. Zhuo, Q.; Zhou, X.; Kang, H.; Chen, Z.; Yang, Y.; Han, F.; Zhang, H.;* Xia, H.* Synthesis of Fused Metallaaromatics via Intramolecular C−H Activation of Thiophenes. Organometallics 201635, 1497-1504.

38. Zhuo, Q.;† Chen, Z.;† Yang, Y.; Zhou, X.; Han, F.; Zhu, J.; Zhang, H.;* Xia, H.* Synthesis of Aromatic Ruthenabenzothiophenes via C–H Activation of Thiophenes. Dalton Trans. 201645, 913-917.(Zhuo and Chen contributed equally to this work.)

37. Luo, M.; Zhu, C.; Chen, L.; Zhang, H.;* Xia, H.* Halogenation of Carbyne Complexes: Isolation of Unsaturated Metallaiodirenium Ion and Metallabromirenium Ion. Chem. Sci. 20167, 1815-1818.

36. Zhou, X.; He, X.; Lin, J.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Wang, J.;* Xia, H.* Reactions of Osmium Hydrido Alkenylcarbyne with Allenoates: Insertion and [3 + 2] Annulation. Organometallics 201534, 1742-1750.

35. Wei, Y.; Zhou, X.; Hong, G.; Chen, Z.; Zhang, H.;* Xia, H.* Reactions of Osmapyridinium with Terminal Alkynes. Org. Chem. Front. 2015, 2, 560-568.

34. Chen, J.; Huang, Z.-A.; Hua, Y.; Zhang, H.;* Xia, H. Synthesis of Five-Membered Osmacycles with Osmium–Vinyl Bonds from Hydrido Alkenylcarbyne Complexes. Organometallics 201534, 340-347.

33. Wang, T.; Han, F.; Huang, H.; Li, J.; Zhang, H.;* Zhu, J.; Lin, Z.;* Xia, H.* Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation. Sci. Rep. 20155, 9584.

32. Han, F.; Li, J.; Zhang, H.;* Wang, T.; Lin, Z.;* Xia, H.* Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene. Chem. - Eur. J. 201521, 565-567.

31. Chen, J.;† Huang, Z.-A.;† Hua, Y.; Zhang, H.;* Xia, H. Synthesis of Five-Membered Osmacycles with Osmium–Vinyl Bonds from Hydrido Alkenylcarbyne Complexes. Organometallics 201534, 340-347.(Chen and Huang contributed equally to this work.)

30. Han, F.; Wang, T.; Li, J.; Zhang, H.;* Xia, H.* m-Metallaphenol: Synthesis and Reactivity Studies. Chem. - Eur. J. 201420, 4363-4372.

29. Zhang, H.;* Lin, R.; Li, J.; Xia, H. Interconversion between Ruthenacyclohexadiene and Ruthenabenzene: A Combined Experimental and Theoretical Study. Organometallics 201433, 5606-5609.

28. Zhuo, Q.; Wang T.; Zhou, X.; Zhang, H.* Progresses of Ring Expansion Reaction of Small Transitional Metallacyclic Compounds. Chin. J. Org. Chem. 201434, 1471-1486.

27. Han, F.; Wang, T.; Li, J.; Zhang, H.; Zhang; L.; He, X.;* Xia, H.* Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex. Organometallics 201433, 5301-5307.

26. Wang, T.; Zhu, J.; Han, F.; Zhou, C.; Chen, H.; Zhang, H.;* Xia, H.* Synthesis of Five-membered Osmacycloallenes and Conversion to Six-membered Osmacycloallenes. Angew. Chem., Int. Ed. 201352, 13361-13364.

25. Wang, T.;† Zhang, H.;† Han, F.; Long, L.; Lin, Z.;* Xia, H.* Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization. Angew. Chem., Int. Ed. 201352, 9251-9255. (†Wang and Zhang contributed equally to this work.)

24. Wang, T.;† Zhang, H.;†  Han, F.; Long, L.; Lin, Z.;* Xia, H.* cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study. Chem. - Eur. J. 201319, 10982-10991. (Wang and Zhang contributed equally to this work.)

23. Chen, J.; Zhang, C.; Xie, T.; Wen, T. B.; Zhang, H.;* Xia, H. Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes. Organometallics 201332, 3993-4001.

22. Zhang, C.; Zhang, H.; Zhang, L.; Wen, T. B.; He, X.;* Xia, H.* Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization. Organometallics 201332, 3738-3743.

21. Zhang, C.; Zhang, H.; Wei, A.; He, X.;Xia, H.* Synthesis of Ruthena-polycyclic Complexes by Ruthenium-Vinylcarbene Complex. Acta Chim. Sinica 201371, 1373.

20. Xie, H.; Zhang, H.; Lin, Z.* DFT Studies on the Palladium-Catalyzed Dearomatization Reaction between Chloromethylnaphthalene and the Cyclic Amine Morpholine. Organometallics 201332, 2336-2343.

19. Xie, H.; Zhang, H.; Lin, Z.* DFT Studies on the Mechanisms of Palladium-Catalyzed Intramolecular Arylation of a Silyl C(sp3)–H Bond. New J. Chem. 201337, 2856-2861.

18. Wang, T.;† Zhang, H.;† Han, F.; Long, L.; Lin, Z.;* Xia, H.* Synthesis and Characterization of a Metallapyridyne Complex. Angew. Chem., Int. Ed. 201251, 9838–9841. (Wang and Zhang contributed equally to this work.)

17. Lin, R.; Zhao, J.; Chen, H.; Zhang, H.;* Xia, H.* Interconversion of Metallabenzenes and Cyclic η2-Allene-Coordinated Complexes. Chem. - Asian J. 20127, 1915–1924.

16. Lin, R.; Zhang, H.;* Li, S.; Wang, J.; Xia, H.* New Highly Stable Metallabenzenes via Nucleophilic Aromatic Substitution Reaction. Chem. - Eur. J. 201117, 4223–4231. (Inside Cover)

15. Lin, R.; Zhang, H.;* Cao, X.-Y.; Xia, H. The Electrophilic Aromatic Addition and Substitution Reactions of Metallabenzenes. Journal of Xiamen University(Natural Science) 201150 (S1), 1-4.

14. Lin, R.; Zhang, H.; Li, S.*; Chen, L.; Zhang, W.; Wen, T. B.; Zhang, H.;* Xia, H.* pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene with l- and d-Cysteine. Chem. - Eur. J. 201117, 2420-2427.(This article has been highlighted by ACS "Noteworthy Chemistry".)

13. Zhang, H.;* Lin, R.; Luo, M.; Xia, H.* Synthesis and Characterization of Stable Osmafuran Starting from HC≡CCH(OH)C≡CH and OsHCl(CO)(PPh3)3, Sci. China: Chem201053, 1978-1981. 

12. Zhang, H.;* Lin, R.; Hong, G.; Wang, T.; Wen, T. B.; Xia, H.* Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes. Chem. - Eur. J. 201016, 6999-7007.

11. Wang, T. ; Li, S.; Zhang H.; Lin R.; Han F.; Lin Y.; Wen T. B.; Xia, H.* Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole. Angew. Chem., Int. Ed. 200948, 6453-6456.

10. Zhang, H.; Wu, L.; Lin, R.; Zhao, Q.; He, G.; Yang, F.; Wen, T. B.; Xia, H.* Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3 Substituents. Chem. - Eur. J. 200915, 3546-3559.

9. Wu, L.; Feng, L.; Zhang, H.; Liu, Q.; He, X.; Yang, F.; Xia, H.* Synthesis and Characterization of a Novel Dialdehyde and Cyclic Anhydride. J. Org. Chem200873, 2883–2885.

8. Gong, L.; Lin, Y.; Wen, T. B.; Zhang, H.; Zeng, B.; Xia, H.* Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction. Organometallics 200827, 2584–2589.

7. Gong, L.; Lin, Y.; He, G.; Zhang, H.; Wang, H.; Wen, T. B.;* Xia, H.* Synthesis and Characterization of an Air-Stable p-Osmaphenol. Organometallics 200827, 309–311.

6. Zhang, H.; Feng, L.; Gong, L.; Wu, L.; He, G.; Wen, T. B.; Yang, F.; Xia, H.* Synthesis and Characterization of Stable Ruthenabenzenes Starting from HCCCH(OH)CCH. Organometallics 200726, 2705-2713.

5. Gong, L.; Wu, L.; Lin, Y.; Zhang, H.; Yang, F.; Wen, T.; Xia, H.* Synthesis and Characterization of a Bimetallic Iridium Complex with a Ten sp2-Carbon Chain Bridge. Dalton Trans. 2007, 4122-4125.

4. Zhang, H.; Xia, H.;* He, G.; Wen, T. B.; Jia, G.* Synthesis and Characterization of Stable Ruthenabenzenes. Angew. Chem., Int. Ed200645, 2920-2923.(VIP).(This article has been highlighted by ACS "Heart Cut".

3. Xia, H.;* He, G.; Zhang, H.; Wen, T. B.; Sung, H. H. Y.; Williams, I. D.; Jia, G.* Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3 (X = Cl, Br). J. Am. Chem. Soc. 2004126, 6862-6863.(This article has been highlighted by ACS "Chemical & Engineering News". 

2. Zhang, H.; He, G.; Xia, H.* Progress of Study on Linear Carbon Bridged Organometallic Molecular Wires. Chin. J. Org. Chem. 200424, 355-365.

1. Zhang, H.; He, X.;* Ding, M. Application of Pessure-Driven Membrane in Meallurgical Industry. Journal of Functional Materials (Chinese) 200233, 588-569, 593.

 
上一篇:He Xumin
下一篇:Chen Jiangxi