Group

Zhang Hong


Education

09/2001–08/2007

Doctorate Student, Organic Chemistry,  College of Chemistry and Chemical Engineering, Xiamen University, China, Supervisor: Prof. Haiping Xia

09/1997-07/2001

Undergraduate Student, Material Science, College of Chemistry and Chemical Engineering, Xiamen University, China, Supervisor: Prof. Haiping Xia


Research Experience

09/2007–08/2011

Assistant Professor, Organic Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, China

04/2012–04/2013

Postdoctoral Fellow, Computational Chemistry, Department of Chemistry, The Hong Kong University of Science& Technology, Hong Kong, Supervisor: Prof. Zhenyang Lin 

08/2011–present

Associate Professor, Organic Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, China


 

Contact me:

Lu Jiaxi Building 742, College of Chemistry and Chemical Engineering, Xiamen University
Tel:0592-2184520
Email:zh@xmu.edu.cn
 

Publication:

46. Zhou, X.; Huang, F.; Tang, C.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Xia, H. A Missing Member of Conjugated N-Heterocycles: Realizing Pyrido[1,2-Α]azepine by Reacting Ruthenium Alkenylcarbene Complex with Alkyne. Chem. Commun. 2018, 54, 4009-4012.

45. Zhou, X.; Zhang, H.* Reactions of Metal-Carbon Bonds within Six-Membered Metallaaromatic Rings. Chem. Eur. J. 201824, 8962-8973.

44.  Hua, Y.; Zhang, H.;* Xia, H.* Aromaticity: History and Development. Chin. J. Org. Chem. 201838, 11-28.

43. Zhuo, Q.; Lin, J.; Hua, Y.; Zhou, X.; Shao, Y.; Chen, S.; Chen, Z.; Zhu, J.; Zhang,H.; Xia, H.* Multiyne Chains Chelating Osmium via Three Metalcarbon σ Bonds. Nat. Commun. 20178, 1912.

42. Long, L.; Zhou, X.; Wang, T.; Chen, Z.; Zhang, H.;* Xia, H.* Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine. Organometallics 201736, 4184−4190.

41. Huang, Z.; Lan, Q.; Hua, Y.; Chen, Z.; Zhang, H.;* Lin, Z.;* Xia, H.* Color-Tuning Strategy for Iridapolycycles [(N-N)Ir(C-C)ClPPh3]+ by the Synergistic Modifications on Both the C-C and N-N Units. Organometallics 201736, 4802–4809.

40. Luo, M.; Long, L.; Zhang, H.;* Yang, Y.; Hua, Y.; Liu, G.; Lin, Z.;* Xia, H.* Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates. J. Am. Chem. Soc2017,139, 1822-1825.

39. Chen, J.; Huang, Z.-A.; Lu, Z.; Zhang, H.;* Xia, H.* Synthesis of Cyclic Vinylidene Complexes and Azavinylidene Complexes by Formal [4+2] Cyclization Reactions. Chem. Eur. J. 2016, 22, 5363-5375.

38. Zhuo, Q.; Zhou, X.; Kang, H.; Chen, Z.; Yang, Y.; Han, F.; Zhang, H.;* Xia, H.* Synthesis of Fused Metallaaromatics via Intramolecular C−H Activation of Thiophenes. Organometallics 201635, 1497-1504.

37. Zhuo, Q.; Chen, Z.; Yang, Y.; Zhou, X.; Han, F.; Zhu, J.; Zhang, H.;* Xia, H.* Synthesis of Aromatic Ruthenabenzothiophenes via C–H Activation of Thiophenes. Dalton Trans201645, 913-917.

36. Luo, M.; Zhu, C.; Chen, L.; Zhang, H.;* Xia, H.* Halogenation of Carbyne Complexes: Isolation of Unsaturated Metallaiodirenium Ion and Metallabromirenium Ion. Chem. Sci. 20167, 1815-1818.

35. Zhou, X.; He, X.; Lin, J.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Wang, J.;* Xia, H.* Reactions of Osmium Hydrido Alkenylcarbyne with Allenoates: Insertion and [3 + 2] Annulation. Organometallics 2015, 34, 1742-1750.

34. Wei, Y.; Zhou, X.; Hong, G.; Chen, Z.; Zhang, H.;* Xia, H.* Synthesis of Five-Membered Osmacycles with Osmium–Vinyl Bonds from Hydrido Alkenylcarbyne Complexes. Organic Chemistry Frontiers 2015, 2, 560.

33. Wang, T.; Han, F.; Huang, H.; Li, J.; Zhang, H.;* Zhu, J.; Lin, Z.;* Xia, H.* Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation. Sci. Rep. 20155, 9584.

32. Han, F.; Li, J.; Zhang, H.*; Wang, T.; He, X*; Xia, H.* Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene. Chem. Eur. J201521, 565-567.

31. Chen, J.; Huang, Z.-A.; Hua, Y.; Zhang, H.*; Xia, H. Synthesis of Five-Membered Osmacycles with Osmium–Vinyl Bonds from Hydrido Alkenylcarbyne Complexes. Organometallics 201534, 340-347.

30. Han, F.; Wang, T.; Li, J.; Zhang, H.*; Xia, H.* m-Metallaphenol: Synthesis and Reactivity Studies. Chem. Eur. J201420, 4363-4372.

29. Zhang, H.*; Lin, R.; Li, J.; Xia, H. Interconversion between Ruthenacyclohexadiene and Ruthenabenzene: A Combined Experimental and Theoretical Study. Organometallics 201433, 5606-5609.

28. Zhuo, Q.; Wang T.; Zhou, X.; Zhang, H.* Progresses of Ring Expansion Reaction of Small Transitional Metallacyclic Compounds. Chin. J. Org. Chem. 201434, 1471-1486.

27. Han, F.; Wang, T.; Li, J.; Zhang, H.; Zhang; L.; He, X*; Xia, H.* Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex. Organometallics 201433, 5301-5307.

26. Wang, T.; Zhu, J.; Han, F.; Zhou, C.; Chen, H.; Zhang, H.*; Xia, H.* Synthesis of Five-membered Osmacycloallenes and Conversion to Six-membered Osmacycloallenes. Angew. Chem. Int. Ed. 201352, 13361-13364.

25. Wang, T.; Zhang, H.; Han, F.; Long, L.; Lin, Z.*; Xia, H.* Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization. Angew. Chem. Int. Ed. 201352, 9251-9255. (共同第一作者)

24. Wang, T.; Zhang, H.; Han, F.; Long, L.; Lin, Z.*; Xia, H.*, cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study. Chem. Eur. J. 201319, 10982-10991. (共同第一作者)

23. Chen, J.; Zhang, C.; Xie, T.; Wen, T. B.; Zhang, H.*; Xia, H. Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes. Organometallics 201332, 3993-4001.

22. Zhang, C.; Zhang, H.; Zhang, L.; Wen, T. B.; He, X.*; Xia, H.* Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization. Organometallics 201332, 3738-3743.

21. Zhang, C.; Zhang, H.; Wei, A.; He, X.;Xia, H.* Synthesis of Ruthena-polycyclic Complexes by Ruthenium-Vinylcarbene Complex. Acta Chim. Sinica 2013, 71, 1373.

20. Xie, H.; Zhang, H.; Lin, Z.* DFT Studies on the Palladium-Catalyzed Dearomatization Reaction between Chloromethylnaphthalene and the Cyclic Amine Morpholine. Organometallics 201332, 2336-2343.

19. Xie, H.; Zhang, H.; Lin, Z.* DFT Studies on the Mechanisms of Palladium-Catalyzed Intramolecular Arylation of a Silyl C(sp3)–H Bond. New J. Chem. 201337, 2856-2861.

18. Wang, T.; Zhang, H.; Han, F.; Long, L.; Lin, Z.*; Xia, H.* Synthesis and Characterization of a Metallapyridyne Complex. Angew. Chem. Int. Ed. 201251, 9838–9841. (共同第一作者)

17. Lin, R.; Zhao, J.; Chen, H.; Zhang, H.*; Xia, H.* Interconversion of Metallabenzenes and Cyclic η2-Allene-Coordinated Complexes. Chem. - Asian J. 20127, 1915–1924.

16. Lin, R.; Zhang, H.*; Li, S.; Wang, J.; Xia, H.* New Highly Stable Metallabenzenes via Nucleophilic Aromatic Substitution Reaction. Chem. Eur. J201117, 4223–4231. (Inside Cover)

15. Lin, R.; Zhang, H.;* Cao, X.-Y.; Xia, H. The Electrophilic Aromatic Addition and Substitution Reactions of Metallabenzenes. Journal of Xiamen University(Natural Science) 201150 (S1), 1-4.

14. Lin, R.; Zhang, H.; Li, S.*; Chen, L.; Zhang, W.; Wen, T. B.; Zhang, H.*; Xia, H.* pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene with l- and d-Cysteine. Chem. Eur. J. 201117, 2420-2427.(美国化学会“Noteworthy Chemistry”栏目针对本文发评论文章)

13. Zhang, H.;* Lin, R.; Luo, M.; Xia, H.* Synthesis and Characterization of Stable Osmafuran Starting from HC≡CCH(OH)C≡CH and OsHCl(CO)(PPh3)3, Sci. China: Chem201053, 1978-1981. 

12. Zhang, H.*; Lin, R.; Hong, G.; Wang, T.; Wen, T. B.; Xia, H.* Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes. Chem. Eur. J201016, 6999-7007.

11. Wang, T. ; Li, S.; Zhang H.; Lin R.; Han F.; Lin Y.; Wen T. B.; Xia, H.* Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole. Angew. Chem. Int. Ed. 200948, 6453-6456.

10. Zhang, H.; Wu, L.; Lin, R.; Zhao, Q.; He, G.; Yang, F.; Wen, T. B.; Xia, H.* Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3 Substituents. Chem. Eur. J. 200915, 3546-3559.

9. Wu, L.; Feng, L.; Zhang, H.; Liu, Q.; He, X.; Yang, F.; Xia, H.* Synthesis and Characterization of a Novel Dialdehyde and Cyclic Anhydride. J. Org. Chem200873, 2883–2885.

8. Gong, L.; Lin, Y.; Wen, T. B.; Zhang, H.; Zeng, B.; Xia, H.* Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction. Organometallics 200827, 2584–2589.

7. Gong, L.; Lin, Y.; He, G.; Zhang, H.; Wang, H.; Wen, T. B.;* Xia, H.* Synthesis and Characterization of an Air-Stable p-Osmaphenol. Organometallics 200827, 309–311.

6. Zhang, H.; Feng, L.; Gong, L.; Wu, L.; He, G.; Wen, T. B.; Yang, F.; Xia, H.* Synthesis and characterization of stable ruthenabenzenes starting from HCºCCH(OH)CºCH. Organometallics 200726, 2705-2713.

5. Gong, L.; Wu, L.; Lin, Y.; Zhang, H.; Yang, F.; Wen, T.; Xia, H.* Synthesis and Characterization of a Bimetallic Iridium Complex with a Bridge of Ten sp2-Carbon Chain. Dalton Trans. 2007, 4122-4125.

4. Zhang, H.; Xia, H.*; He, G.; Wen, T. B.; Jia, G.* Synthesis and characterization of stable ruthenabenzenes. Angew. Chem. Int. Ed200645, 2920-2923.(VIP).(美国化学会“Heart Cut”栏目针对本文发表评论文章)

3. Xia, H.;* He, G.; Zhang, H.; Wen, T. B.; Sung, H. H. Y.; Williams, I. D.; Jia, G.* Osmabenzenes from the reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3 (X = Cl, Br). J. Am. Chem. Soc. 2004126, 6862-6863.(美国化学会 “Chemical & Engineering News”栏目针对本文发表评论文章)

2. Zhang, H.; He, G.; Xia, H.* Progress of Study on Linear Carbon Bridged Organometallic Molecular Wires. Chin. J. Org. Chem. 200424, 355-365.

1. Zhang, H.; He, X.;* Ding, M. Application of pessure-driven membrane in meallurgical industry. Journal of Functional Materials (Chinese) 200233, 588-569, 593.

He Xumin

He Xumin obtained her B.S. in Chemistry in 1985 and obtained her M.S. in 1990 from Xiamen University. From 1995 to 1999, she worked in Hong Kong Baptist University, for her Ph.D.
 

Contact me:

Email: hejin@xmu.edu.cn
 

Papers Published:

17. Zhang, C.; Zhang, H.; Zhang, L.; Wen, T. B.; He, X.;* Xia, H.* Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization. Organometallics 201332, 3738-3743.

16. Xu, X.-X.; Zhou, C.-L.; Zeng, B.-R.;* Xia, H.-P.; Lan, W.-G.; He, X.-M.* Structure and properties of polyamidoamine/polyacrylonitrile composite nanofiltration membrane prepared by interfacial polymerization. Sep. Purif. Technol. 201296, 229-236.

15. Zhao, Q.; Gong, L.; Xu, C.; Zhu, J.;* He, X.; Xia, H.* Stable Isoosmabenzenes from a Formal [3+3] Cycloaddition Reaction of Metal Vinylidene with Alkynols. Angew. Chem. Int. Ed. 201150, 1354-1358.

14. He, X.; Gong, L.; Kräling, K.; Gründler, K.; Frias, C.; Webster, R. D.; Meggers, E.;* Prokop, A.;* Xia, H.* Unusual η2-Allene Osmacycle with Apoptotic Properties. ChemBioChem 201011, 1607-1613. 

13. Lin, Y.; Xu, H.; Gong, L.; Wen, T. B.; He, X.-M.;* Xia, H.* C-H Bond Activation and Subsequent C(sp2)-C(sp3) Bond Formation: Coupling of Bromomethyl and Triphenylphosphine in an Iridium Complex. Organometallics 201029, 2904–2910.

12. Xiong, X.;* Duan, J.; Zou, W.; He, X.; Zheng, W. A pH-sensitive regenerated cellulose membrane. J. Membr. Sci. 2010363, 96–102.

11. Han Q.-R.; Wang B.-X.; Ding M.-T., He, X.-M.* Effect of Cu2+ upon the Fluorescent Properties of Dendrimer PAMAM-FCD. Chemical Journal of Chinese Universities (Chinese) 201031, 181-185.

10. Gong, L.; Chen, Z.; Lin, Y.; He, X.;* Wen, T. B.; Xu, X.; Xia, H.* Osmabenzenes from Osmacycles Containing an η2-Coordinated Olefin. Chem. Eur. J. 200915, 6258-6266.

9. He, X.-M.;* Xie, Q.-L.; Liu, J.; Lan, W.-G.; Xia, H.-P. Photocatalytic activity of size and phase selective TiO2 nanoparticles prepared by the membrane processing. Sep. Purif. Technol. 200968, 153–158.

8. Xie, Q.-L.; Liu, J.; Xu, X.-X.; Han, G.-B.; Xia, H.-P.; He, X.-M.* Size Separation of Fe2O3 Nanoparticles via Membrane Processing. Sep. Purif. Technol. 200966, 148-152.

7. Lin, Y.; Gong, L.; Xu, H.; He, X.; Wen, T. B.; Xia, H.*  Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran. Organometallics 200928, 1524-1533.

6. Han Q.-R.; Wang B.-X.; He, X.-M.*; Ding M.-T., Xia H.-P. Synthesis and Fluorescent Properties of Dendrimer PAMAM(1G)-FCD. Chemical Journal of Chinese Universities (Chinese) 200930, 629-631.

5. Me, X.-M.;* Xie, Q.-L.; Xia, H.-P.; Lan, W.-G. Application of Nanofiltration Process in 5′- GMP Production. Desalination 2008225, 322-328.

4. Wu, L.; Feng, L.; Zhang, H.; Liu, Q.; He, X.; Yang, F.; Xia, H.* Synthesis and Characterization of a Novel Dialdehyde and Cyclic Anhydride. J. Org. Chem. 200873, 2883-2885.

3. He, X.-M.;* Yang P.-X.; Chen Z.-N.; Fu G.; Xu X.; Density Functional Method Studies on Configuration and Electronic Structure of R-ReO3. Chemical Journal of Chinese Universities (Chinese) 200829, 2267-2272.

2. Huang, T. H.; Yu, Z. J.;* He, X. M.;* Huang, M. H.; Chen, L. F.; Xia, H. P.; Zhang, L. T. One-pot Synthesis and Characterization of a New, Branched Polycarbosilane Bearing Allyl Groups. Chin. Chem. Lett. 200718, 754-757.

1. He, X. M.; Zheng, W.; Yang, P. X.; Xia, H. P.* 9-Anthracenecarboxaldehyde Functionalized Second Generation Poly(amidoamine) Dendrimers: Synthesis and Metal Absorption. Chin. Chem. Lett. 200617, 1251-1254.

 

Patents:

1. 一种XXXX的制备方法, National defense patent, Patent Number: ZL 200710081727.7, The first inventor.
2. 纳米级TiO2水合物颗粒—水体系中离子脱除方法, invention patent, Patent Number: ZL031030742, The first inventor.
3. 纳米级二氧化锆水合物颗粒—水体系中离子脱除方法, invention patent, Patent Number: ZL200410055359.5, The second inventor.


Teaching Meterial:

1. 董炎明, 何旭敏. 高分子化学与物理习题汇编. 北京:科学出版社, 2013.
2. 何旭敏, 董炎明. 高分子化学学习指导. 北京: 科学出版社, 2007.
3. 何旭敏等. 悬浮聚合法制备聚乙烯苯及离子交换树脂的制备、表征和应用等二个实验. 见: 王尊本主编. 综合化学实验. 第二版. 北京: 科学出版社, 2007

Lin Yumei

Yumei Lin obtained her B.S. in chemistry from Quanzhou Normal University in 2005. From 2005 to 2010, she worked with Prof. Haiping Xia in Xiamen University for her Ph.D. From 2010 to 2012, she worked with Prof. Stefanie Dehnen in Marburg University in Germany as a Humboldt Alexander fellow. In 2013, she joined Xiamen University as an Associate Professor. Her research focuses on the controllable assembly and applications of novel aromatic compounds and nanoclusters.
 

Selected Recent Publications:

19. Guan, Z.-J.; Zeng, J.-L.; Nan, Z.-A.; Wan, X.-K.; Lin, Y.-M.;* Wang, Q.-M.Thiacalix[4]arene: New Protection for Metal Nanoclusters. Sci. Adv. 20162, e1600323.

18. Zeng, J.-L.; Guan, Z.-J.; Du,Y.; Nan, Z.-A.; Lin, Y.-M.;* Wang, Q.-M.* Chloride-Promoted Formation of a Bimetallic Nanocluster Au80Ag30 and the Total Structure Determination. J. Am. Chem. Soc. 2016138, 7848−7851.

17. Wang, J.-Y.; Liu, K.-G.; Guan, Z.-J.; Nan, Z.-A.; Lin, Y.-M.;* Wang, Q.-M.* [MnIIIMnIV2Mo14O56]17–: A Mixed-Valence Meso-Polyoxometalate Anion Encapsulated by a 64-Nuclearity Silver Cluster. Inorg. Chem. 201655, 6833–6835.

16. Liu, K.-G.; Liu, X-Y.; Guan, Z.-J; Shi, K;* Lin, Y.-M.* Wang, Q.-M. The Transformation of Polyoxometalate in the Formation of  Intercluster Compound [Ag41(α-SiW10O37)(tBuC=C)27(CH3CN)3][β-SiW12O40]. Chem. Commun201652, 3801-3804.

15. Wang, Q.-M.;* Lin, Y.-M.; Liu, K.-G. Role of Anions Associated with the Formation and Properties of Silver Clusters. Acc. Chem. Res.201548, 1570–1579.

14. Liu, K.-G.; Chen, S.-K.; Lin, Y.-M.;* Wang, Q.-M.* An Organic Anion Template: A 24-Nucleus Silver Cluster Encapsulating a Squarate Dimer. Chem. Commun.201551, 9896-9898.

13. Lin, Y.-M.;* Guan, Z-J; Liu, K.-G.; Jiang Z.-G.; Wang, Q.-M.,* Assembly of Silver Alkynyl Compounds with Various Nuclearities. Dalton Trans. 201544, 2439-2446.

12. Jiang, Z.-G.; Shi, K.; Lin, Y.-M.;* Wang, Q.-M.* [Ag70(PW9O34)2(tBuC≡RC)44(H2O)2]8+: Ionothermal Synthesis of a Silver Cluster Encapsulating Lacunary Polyoxometalate Ions. Chem. Commu. 201450, 2353-2355.

11. Zhou, X.; Zhang, C; Lin, Y.-M, He, X; Zhang, Y; Wang, J; Xia, H.1,2-Migration in the Reactions of Ruthenium Vinylcarbene with Propargyl Alcohols. Org. Chem. Front. 20141, 1077-1082.

10. Lin, Y.-M.; Zhen, L.; Chang, S.-S.; Wang, Q.-M.* Directed formation of tri-connected Cu(I) coordination polymers, CrystEngComm201315, 9372-9376.

9. Lin, Y.; Xie, D.; Massa, W. Dehnen, S.* Reversible Changes in Structural Dimensionality of Selenostannates in Ionic Liquids: Formation, Structures, Stability and Photocunductivity, Chem. Eur. J. 201319, 8806-8813.

8. Lin, Y.; Massa, W. Dehnen, S.* “Zeoball” [Sn36Ge24Se132]24-: A Molecular Anion with Zeolite-Related Composition and Spherical Shape, J. Am. Chem. Soc. 2012134, 4497-4450.

7. Lin, Y.; Massa, W. Dehnen, S.* Controlling the Assembly of Chalcogenides Anions in Ionic Liquids: From Binary Ge/Se Through Ternary Ge/Sn/Se to Binary Sn/Se Frameworks, Chem. Eur. J. 201218, 13427-13434.

6. Lin, Y.; Dehnen, S.* [BMIm]4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-framework Structure, Inorg. Chem. 201150, 7913-7915.

5. Lin, Y.; Xu, H; Gong, L; Wen, T. B; He, X. M;* Xia, H.* C–H Bond Activation and Subsequent C(sp2)–C(sp3) Bond Formation : Coupling of Bromomethyl and Triphenylphosphine in an Iridium complex, Organometallics 201029, 2904-2910.

4. Lin, Y.; Gong, L; Xu, H; He, XM; Wen, T. B; Xia, H.* Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran, Organometallics 200928, 1524-1533.

3. Wang, T;  Li, S; Zhang, H; Lin, R; Han, F;  Lin, Y.;  Wen, T. B; Xia, H.* Annelation Reaction of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole, Angew. Chem. Int. Ed. 200948, 6453-6456.

2. Gong, L; Chen, Z; Lin, Y.; He, X. M*; Wen, T. B; Xu, X; Xia, H.* Osmabenzenes from Osmacycles Containing an η2-Coordinated Olefin, Chem. Eur. J200915, 6258-6266.

1. Gong, L; Lin, Y.; Wen, T. B*; Xia, H.* Synthesis of Coordinated η2-α,β-Unsaturated Ketone Osmacycles from an Osmium-coordinated Alkyne Alcohol Complex, Organometallics 200928, 1101-1111.


Chen Jiangxi

chen jiangxi

Current Research:

1) Synthesis, Preparation and Properties of Organometallics and metallopolymer Materials
2) Synthesis, Preparation and Properties of Metal-Containing Biomaterials
3) Development and Research of Novel Functional Material 

 

Contact me:

Email: chenjx@xmu.edu.cn
 
 

Papers Published:

14. He, X.;* He, X.; Li, S.; Zhuo, K.; Qin, W.; Dong, S.; Chen, J.; Ren, L.; Liu, G.; Xia, H.* Amphipathic Metal-containing Macromolecules with Photothermal Properties. Polym. Chem.20178, 3674-3678.

13. He, G.; Wu, L.; Bai, W.; Chen, J.;* Sung, H. H. Y.; Williams, I. D.; Lin, Z.;* Jia, G.* Synthesis and Reactivities of Polyhydrido Osmium Arylsilyl Complexes Prepared from OsH3Cl(PPh3)3, Organometallics 201736, 3729-3738.

12. Lu, Z.; Zhu, C.; Cai, Y.; Zhu, J.; Hua, Y.; Chen, Z.; Chen, J.;* Xia, H.* Metallapentalenofurans and Lactone-Fused Metallapentalynes. Chem. Eur. J. 201723, 6426-6431.

11. Chen, J.; Lee, K. H.; Sung, H. H.; Williams, I. D.;* Lin, Z.;* Jia, G.* Synthesis and Characterization of Dirhenadehydro[12]annulenes. Angew. Chem. Int. Ed. 201655, 7194-7198.

10. Chen, J.; Lee, K.-H.; Wen, T.; Gao, F.; Sung, H. H. Y.; Williams, I. D.;* Lin, Z.;* Jia, G.* Rearrangement of Metallabenzynes to Chlorocyclopentadienyl Complexes. Organometallics 201534, 890-896.

9. Chen J.; Jia G.* Recent Development in the Chemistry of Transition Metal-containing Metallabenzenes and Metallabenzynes, Coord. Chem. Rev. 2013257, 2491-2521.

8. Chen J.; He G.; Jia G.* Synthesis and Chemical Properties of Metallabenzynes. Chin. J. Org. Chem. 2013, 33, 792-798.

7. Chen, J.; Shi, C.; Sung, H. H.; Williams, I. D.; Lin, Z.;* Jia, G.* Synthesis and Characterization of Rhenabenzyne Complexes, Chem. Eur. J. 201218, 14128-14139.

6. Chen, J.; Shi, C.; Sung, H. H.-Y.; Williams, I. D.; Lin, Z.;* Jia, G.* Hydrogen Shift Reactions of Rhenium Hydrido Carbyne Complexes, Organometallics 201231, 1817-1824.

5. Chen, J.; Sung, H. H.; Williams, I. D.; Lin, Z.;*Jia, G.* Synthesis and Characterization of a Rhenabenzyne Complex. Angew. Chem. Int. Ed. 201150, 10675-10678.

4. Chen, J.; Shi, C. ; Sung, H. H.; Williams, I. D., Lin, Z.* and Jia, G.* Conversion of Metallabenzynes into Carbene Complexes. Angew. Chem. Int. Ed. 201150, 7295-7299.

3. Chen, J.; Sung, H. H.-Y.; Williams, I. D.; Jia, G.* Hydrolysis of Osmium and Ruthenium Carbyne Complexes. Organometallics 201130, 6159-6165. 

2. Chen, J.; He, G.; Sung, H. H.-Y.; Williams, I. D.; Lin, Z.; Jia, G.* Rhenium Carbyne and η2-Vinyl Complexes from One-Pot Reactions of ReH5(PMe2Ph)3 with Terminal Alkynes. Organometallics 201029, 2693-2701.

1. Chen, J.; He, G.; Liao, Z.; Zeng, B.; Ye, J.; Chen, L.; Xia, H.;* Zhang, L. Control of structure formation of polycarbosilane synthesized from polydimethylsilane by Kumada rearrangement, J. Appl. Polym. Sci. 2008108, 3114-3121.
 

Cao Xiaoyu

曹晓宇
Xiao-Yu Cao obtained his B.S. in chemistry from Peking University in 2003. From 2004 to 2011, he worked with Prof. Jean-Marie Lehn in Universite de Strasbourg, France, for his Ph.D. and with Prof. E. W. (Bert) Meijer in Eindhoven University of Technology, The Netherlands, as a Marie-Curie Intra-European Fellow. In 2011, he joined Xiamen University as an Associate Professor. His research focuses on the design, synthesis, controllable assembly, and applications of novel aromatic molecules.
 

Papers Published:

16. Cao, X.-Y.; Harrowfield, J.; Nitschke, J.; Ramírez, J.; Stadler, A.-M.; Kyritsakas-Gruber, N.; Madalan, A.; Rissanen, K.; Russo, L.; Vaughan, G.; Lehn, J.-M.* Generation of [2×2] Grid Metallosupramolecular Architectures from Preformed Ditopic Bis(acylhydrazone) Ligands and through Component Self-Assembly. Eur. J. Inorg. Chem.20072007, 2944-2965.

15. Zhou, Y.; Liu, W.-J.; Zhang, W.; Cao, X.-Y.; Zhou, Q.-F.; Ma, Y.-G.*; Pei, J.* Selective Oxidative Cyclization by FeCl3 in the Construction of 10H-Indeno[1,2-b]triphenylene Skeletons in Polycyclic Aromatic Hydrocarbons. J. Org. Chem. 200671, 6822-6828.

14. Cao, X.-Y.; Zi, H.; Zhang, W.; Lu, H.; Pei, J.* Star-Shaped and Linear Nanosized Molecules Functionalized with Hexa-peri-hexabenzocoronene: Synthesis and Optical Properties. J. Org. Chem. 200570, 3645-3653.

13. Zhang, W; Cao, X.-Y.; Zi, H.; Pei, J.* Single-Molecule Nanosized Polycyclic Aromatics with Alternant Five- and Six-Membered Rings: Synthesis and Optical Properties. Org. Lett. 20057, 959-962.

12. Yu, G.; Cao, X.-Y.; Chen, C.; Zi, H.; Lu, H.; Lee, C.; Pei, J.* Novel Efficient Blue Light-Emitting Conjugated Polymers: Synthesis, Optical Properties, and Thermal Optical Stability. Proc. SPIE-Int. Soc. Opt. Eng. 20055632 (Light-Emitting Diode Materials and Devices), 7-16.

11. Cao, X. Y.; Zhang, W.; Zi, H.; Pei, J.* π-Conjugated Twin Molecules Based on Truxene: Synthesis and Optical Properties. Org. Lett. 20046, 4845-4848.

10. Cao, X.-Y.; Zhou, X.-H.; Zi, H.; Pei, J.* Novel Blue-Light-Emitting Truxene-Containing Hyperbranched and Zigzag Type Copolymers: Synthesis, Optical Properties, and Investigation of Thermal Spectral Stability. Macromolecules 200437, 8874-8882.

9. Cao, X. Y.; Liu, X. H.; Zhou, X. H.; Zhang, Y.; Jiang, Y.; Cao, Y.; Cui, Y. X.; Pei, J.* Giant Extended π-Conjugated Dendrimers Containing the 10,15-Dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene Chromophore: Synthesis, NMR Behavior, Optical Properties, and Electroluminescence. J. Org. Chem. 200469, 6050-6058.

8. Chen, Y.; Zhang, J.; Chen, J.; Cao, X. Y.; Wang, J.; Zhao, Y. F.* Sensitivity Improvement of Amino Acids by N-Terminal Diisopropyloxyphosphorylation in Electrospray Ionization Mass Spectrometry. Rapid Commun. Mass Spectrom. 200418, 469-473.

7. Chen, H.; He, M.;* Cao, X.; Zhou, X.; Pei, J. Efficient Matrix-Assisted Laser Desorption/Ionization Method for Fully π-Conjugated Dendrimers. Rapid Commun. Mass Spectrom. 200418, 367-370.

6. Cao, X. Y.; Zhang, W. B.; Wang, J. L.; Zhou, X. H.; Lu, H.; Pei, J.* Extended π-Conjugated Dendrimers Based on Truxene. J. Am. Chem. Soc. 2003125, 12430-12431.

5. Pei, J.;* Wang, J. L.; Cao, X. Y.; Zhou, X. H.; Zhang, W. B. Star-Shaped Polycyclic Aromatics Based on Oligothiophene-Functionalized Truxene: Synthesis, Properties, and Facile Emissive Wavelength Tuning. J. Am. Chem. Soc. 2003125, 9944-9945.

4. Pei, J.;* Ni, J.; Zhou, X.-H.; Cao, X.-Y.; Lai, Y.-H. Regioregular Head-to-Tail Oligothiophene-Functionalized 9, 9'-Spirobifluorene Derivatives. 2. NMR Characterization, Thermal Behavior, and Electrochemical Properties. J. Org. Chem. 200267, 8104-8113.

3. Chen, J.; Zhang, Y.; Cao, X.-Y.; Wang, J.; Chen, Y.; Zhao, Y.-F.* Monitoring the Hydrolysis of p-Nitrophenyl Acetate Catalyzed by Seryl-Histidine with Electrospray Ionization Mass Spectrometry. Chin. J. Chem. 200220, 1097-1101.

2. Pei, J.;* Ni, J.; Zhou, X.-H.; Cao, X.-Y.; Lai, Y.-H. Head-to-Tail Regioregular Oligothiophene-Functionalized 9,9'-Spirobifluorene Derivatives. 1. Synthesis. J. Org. Chem. 200267, 4924-4936.

1. Zhao, C.; Li, P.; Cao, X.; Xi, Z.* Lewis Acid Mediated Reactions of Zirconacyclopentadienes with Aldehydes. One-pot Synthesis Route to Indene and Cyclopentadiene Derivatives from Aldehydes and Benzyne or Alkynes. Chem. Eur. J. 20028, 4292-4298.